Published October 1997 | Version v1
Journal article Metadata-only

Thermal emission of metastable cluster ions of alkali metals

Creators

  • 1. Ivanovskaya Gosudarstvennaya Khimiko-Tekhnologicheskaya Akademiya, Ivanovo (Russian Federation)

Description

Metastable cluster ions of alkali metals (Li, Na, Cs) are registered for the first time in the mass-spectra of thermal emission of inorganic compounds. The (M4+)* and (M5+)* are most intensive among them. It is shown that these ions decay by reactions (M4+)* = M2+ + M2 and (M5+)* = M2+ + M3. The values of kinetic energy released in the process of ions decay are calculated by within of metastable peaks

Abstract (Russian)

В масс-спектрах термической эмиссии неорганических соединений впервые зарегистрированы метастабильные кластерные ионы щелочных металлов (Li, Na, Cs). Наиболее интенсивными из них являются (M4+)* и (M5+)*. Показано, что эти ионы распадаются по реакциям (M4+)* = M2+ + M2 и (M5+)* = M2+ + M3. По величине уширения метастабильных пиков рассчитаны значения кинетической энергии, высвобождаемой в процессе распада ионов

Additional details

Additional titles

Original title (Russian)
Termicheskaya ehmissiya metastabil'nykh klasternykh ionov shchelochnykh metallov

Publishing Information

Journal Title
Khimicheskaya Fizika
Journal Volume
16
Journal Issue
10
Journal Page Range
p. 119-127
ISSN
0207-401X
CODEN
KHFID9

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32041121
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CESIUM COMPOUNDS; ION PAIRS; KINETIC ENERGY; LITHIUM COMPOUNDS; MASS SPECTRA; VANADATES; YTTRIUM COMPOUNDS
Descriptors DEC
ALKALI METAL COMPOUNDS; ENERGY; OXYGEN COMPOUNDS; SPECTRA; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS

Optional Information

Notes
33 refs., 4 figs., 2 tabs.