Use of electromigration method in physicochemical investigations

Presented are the basic results of experiments on studying the complexing of different metals (Sr, Cd, Nb, W, Te, Rh, rare earth elements, actinoids, etc.) with different ligands by the electromigration method. Tested are different ways of calculation of complex stability constants according to electromigration data. An attention is paid to the application of the method for studying equilibriums and kinetics of complexing, migration, hydrolysis and mobility of ions. Some physico-chemical properties of compounds are determined. Shown is the method applicability for studying isotope effects