A green and facile strategy for preparation of novel and stable Cr-doped SrTiO3/g-C3N4 hybrid nanocomposites with enhanced visible light photocatalytic activity
- 1. State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083 (China)
- 2. State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming 650106 (China)
Description
Herein, a green and facile strategy to prepare graphite carbon nitride hybridized chromium doping strontium titanate spheres (CrSTO/g-CN) nanocomposites was reported in this study. The structure characterization clearly indicated that the CrSTO spheres were successfully loaded on the g-C3N4 nano-sheets forming the CrSTO/g-CN heterojunction. Furthermore, the measurement of photocatalytic activity revealed that the as-prepared CrSTO/g-CN hybrid nanocomposites exhibit the considerable stability and significantly enhanced photocatalytic activity for the degradation of rhodamine B under visible light irradiation. Especially the photocatalytic activity of CrSTO/g-CN-70% was almost 4.5 times higher than that of pure g-C3N4 and 3.5 times higher than that of pure Cr-doped SrTiO3 respectively. The enhanced photocatalytic activity of the CrSTO/g-CN hybrid nanocomposites was due to a synergistic effect following the Z-scheme charge transfer mechanism to enhanced charge-separation ability. Therefore, the CrSTO/g-CN hybrid nanocomposites could be of potential interest for water splitting, new fuels synthesis and environmental remediation under natural sunlight. - Highlights: • We synthesized the CrSTO/g-CN nanocomposites via a green and facile method. • CrSTO/g-CN nanocomposites showed an enhanced visible light photocatalytic activity than CrSTO and g-C3N4. • A possible Z-scheme charge transfer mechanism was proposed in our paper
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2015.06.056Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2015.06.056;
- PII
- S0925-8388(15)30171-7;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 647
- Journal Page Range
- p. 456-462
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 47020588
- Subject category
- S77: NANOSCIENCE AND NANOTECHNOLOGY;
- Descriptors DEI
- CARBON NITRIDES; CHROMIUM ADDITIONS; DOPED MATERIALS; GRAPHITE; HETEROJUNCTIONS; IRRADIATION; NANOCOMPOSITES; PHOTOCATALYSIS; REMEDIAL ACTION; STABILITY; STRONTIUM TITANATES; SYNTHESIS; VISIBLE RADIATION
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; ALLOYS; CARBON; CARBON COMPOUNDS; CATALYSIS; CHROMIUM ALLOYS; ELECTROMAGNETIC RADIATION; ELEMENTS; MATERIALS; MINERALS; NANOMATERIALS; NITRIDES; NITROGEN COMPOUNDS; NONMETALS; OXYGEN COMPOUNDS; PNICTIDES; RADIATIONS; SEMICONDUCTOR JUNCTIONS; STRONTIUM COMPOUNDS; TITANATES; TITANIUM COMPOUNDS; TRANSITION ELEMENT ALLOYS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.