Published 2019 | Version v1
Journal article Metadata-only

Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand

Creators

Description

In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.

Availability note (English)

Available from http://vinar.vin.bg.ac.rs/handle/123456789/8381; Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3317

Additional details

Identifiers

URL
http://vinar.vin.bg.ac.rs/handle/123456789/8381; http://cherry.chem.bg.ac.rs/handle/123456789/3317;
DOI
10.1007/s00706-019-02405-7;

Publishing Information

Journal Title
Monatshefte fuer Chemie
Journal Volume
150
Journal Issue
7
Journal Page Range
p. 1241-1248
ISSN
0026-9247

INIS

Country of Publication
Austria
Country of Input or Organization
Serbia
INIS RN
51109586
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S60: APPLIED LIFE SCIENCES;
Descriptors DEI
COUPLING CONSTANTS; DENSITY FUNCTIONAL METHOD; LIGANDS; MAGNETIC PROPERTIES; NICKEL COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; SYNTHESIS; X-RAY DIFFRACTION
Descriptors DEC
CALCULATION METHODS; COHERENT SCATTERING; COMPLEXES; DIFFRACTION; PHYSICAL PROPERTIES; SCATTERING; TRANSITION ELEMENT COMPLEXES; VARIATIONAL METHODS

Optional Information

Notes
OAI: vinar.vin.bg.ac.rs:123456789/8381