Published 1982 | Version v1
Journal article Metadata-only

Study into complexing of anhydrous uranyl chloride with organic o-bases in nonaqueous media. Interaction with aliphatic sulfoxides

Creators

Description

The methods of spectrophotometry, conductometry and calorimetry have been used to investigate interaction of uranyl chloride with dimethyl, diamil, dioctyl sulfoxides in the nonaqueous acetone media. Existence of complexes with 1:1, 1:2, 1:3 composition for dimethyl sulfoxide and with 1:1, 1:2 composition for diamil-, dioctyl sulfoxides is revealed. The constants of formation and dissociation of these complexes are calculated; the enthalpies of their formation in acetone are determined

Additional details

Additional titles

Original title (Russian)
Изучение комплексообразования безводного уранилхлорида с органическими о-основаниями в неводных средах. Взаимодействие с алифатическими сульфоксидами

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
8
Journal Issue
12
Series
Koord. Khim.
Journal Page Range
1673-1676
ISSN
0132-344X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
14805497
Subject category
S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
Descriptors DEI
ACETONE; CHEMICAL PREPARATION; CHLORIDES; DISSOCIATION; DMSO; DPSO; FORMATION HEAT; SULFIDES; URANYL COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; CHALCOGENIDES; CHLORINE COMPOUNDS; COMPLEXES; ENTHALPY; HALIDES; HALOGEN COMPOUNDS; KETONES; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHYSICAL PROPERTIES; REACTION HEAT; SULFOXIDES; SULFUR COMPOUNDS; SYNTHESIS; THERMODYNAMIC PROPERTIES; URANIUM COMPLEXES