Published January 1980
| Version v1
Journal article
Raman spectra of the system PCl5-ZrCl4
Creators
- 1. Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany, F.R.). Anorganisch-Chemisches Inst.
Description
Raman spectra of some solid and molten PCl5-ZrCl4 mixtures have been recorded. ZrCl62- complex ions accompanied by at least one more chlorozirconate species are present in the solid as well as in the melt. The new Raman frequencies are attributed to ZrClsub(5-), which fundamentals are given and assignment is proposed to be analogous to TiClsub(5-). The presence of ZrCl62- and ZrClsub(5-) can be explained by the equilibrium ZrCl62- + PClsub(4+) reversible ZrClsub(5-) + PCl5. (auth.)
Additional details
Additional titles
- Original title (German)
- Ramanspektroskopische Untersuchungen an PCl
- Original subtitle (German)
- Das System PCl_5-ZrCl_4.
Publishing Information
- Journal Title
- Monatsh. Chem.
- Journal Volume
- 111
- Journal Issue
- 1
- Series
- Monatsh. Chem.
- Journal Page Range
- 21-27
- ISSN
- 0026-9247
INIS
- Country of Publication
- Austria
- Country of Input or Organization
- Austria
- INIS RN
- 11557762
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- MOLTEN SALTS; PLATINUM CHLORIDES; RAMAN SPECTRA; SOLIDS; ZIRCONIUM CHLORIDES
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; PLATINUM COMPOUNDS; SALTS; SPECTRA; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS