Use of Salvinia sp on the adsorption of hexavalent chromium
- 1. Federal Universit of Rio de Janeiro, Departament of Chemistry (Brazil)
- 2. National Public Health School Sérgio Arouca -Fiocruz- RJ. (Brazil)
Description
The remotion of hexavalent chromium in the form of chromate in aqueous solution was done using the aquatic plant Salvinia sp as biosorbent. The chemical modification of the Salvinia surface was performed by organosolv adapted method. The untreated Salvinia and the modified were characterized by infrared spectroscopy, Boehm titration, scanning electron microscopy, energy dispersive system, point of zero charge, surface area analysis, and porosity. Batch adsorption experiments were performed to observe the effects of pH, contact time, initial concentration, and temperature on the metal removal process. The characterization results show the chemistry modifically changed the modified Salvinia structure compared with untreated Salvinia. The adsorption test results showed the maximum adsorption capacity of 26.03 mg g−1. The kinetic equilibrium was reached in about 3 h, and the better temperature and pH were 298 K and 7, respectively. The adsorption and kinetic models were Freundlich and pseud-second order, respectively. This study showed the Salvinia sp after the chemical treatment can be used with biosorbent for hexavalent chromate in the form of chromate, being a natural material with low cost and plentiful in the environment.
Additional details
Identifiers
Publishing Information
- Journal Title
- Environmental Science and Pollution Research International
- Journal Volume
- 26
- Journal Issue
- 29
- Journal Page Range
- p. 30463-30471
- ISSN
- 0944-1344
Conference
- Title
- 1. International Research Conference on Sustainable Energy, Engineering, Materials and Environment (IRCSEEME)
- Dates
- 26-28 Jul 2017
- Place
- Newcastle Upon Tyne (United Kingdom)
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 52004582
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S54: ENVIRONMENTAL SCIENCES;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; ADSORPTION; AQUEOUS SOLUTIONS; CHROMATES; CHROMIUM; INFRARED SPECTRA; SCANNING ELECTRON MICROSCOPY; SURFACE AREA
- Descriptors DEC
- CHROMIUM COMPOUNDS; DISPERSIONS; ELECTRON MICROSCOPY; ELEMENTS; HOMOGENEOUS MIXTURES; METALS; MICROSCOPY; MIXTURES; OXYGEN COMPOUNDS; SOLUTIONS; SORPTION; SPECTRA; SPECTROSCOPY; SURFACE PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2019 Springer-Verlag GmbH Germany, part of Springer Nature