Published March 1993 | Version v1
Journal article

Equation of state for ''classical'' helium

  • 1. Department of Chemistry and Division of Engineering, Brown University, Providence, Rhode Island 02912 (United States)

Description

A classical base-line equation of state for fluid helium is calculated from a recent accurate pair potential and a classical statistical-mechanical theory. The range covered is 2.5--1400 K and densities up to 90 mol/dm3. Comparison with experimental data shows how quantum effects in 4He behave in the dense-fluid region. A pseudoclassical calculation based on experimental second virial coefficients fails to account for the high-density quantum effects. The volume expansion caused by zero-point motion can be directly seen in the curvature of the Zeno line

Additional details

Publishing Information

Journal Title
Physical Review. E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Journal Volume
47
Journal Issue
3
Journal Page Range
p. 2193-2196.
ISSN
1063-651X
CODEN
PLEEE8

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
25012122
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
EQUATIONS OF STATE; FLUIDS; HELIUM; QUANTUM MECHANICS; STATISTICAL MECHANICS; TEMPERATURE RANGE 1000-4000 K
Descriptors DEC
ELEMENTS; EQUATIONS; MECHANICS; NONMETALS; RARE GASES; TEMPERATURE RANGE