Published November 2008 | Version v1
Journal article

Lithium insertion-deinsertion mechanism in NbSn2 anode studied by 119Sn Moessbauer spectroscopy

  • 1. UMR 5253 CNRS-UMII-ENSCM-UMI, Equipe AIME, Institut Charles Gerhardt (France)

Description

This article deals with the study of the electrochemical performances and the lithium insertion-deinsertion mechanism by mean of 119Sn Moessbauer spectroscopy of NbSn2. The first discharge shows a plateau at 0.05 V vs. Li+/Li0 corresponding to a displacement reaction with the formation of Li7Sn2. A specific capacity of 487 mAh/g can be reached during this first discharge.

Additional details

Identifiers

Publishing Information

Journal Title
Hyperfine Interactions
Journal Volume
187
Journal Issue
1-3
Journal Page Range
p. 19-26
ISSN
0304-3843
CODEN
HYINDN

Conference

Title
29. international conference on the applications of the Moessbauer effect
Acronym
ICAME 2007
Dates
14-19 Oct 2007
Place
Kanpur (India)

Optional Information

Copyright
Copyright (c) 2008 Springer Science+Business Media B.V.