Published April 1996
| Version v1
Journal article
Synthesis and crystal structure of binary ammonium indium perrhenate and ammonium scandium perrhenate tetrahydrates
- 1. AN SSSR, Moscow (Russian Federation). Inst. Ehlementoorganicheskikh Soedinenij
- 2. Moskovskij Inst. Tonkoj Khimicheskoj Tekhnologii, Moscow (Russian Federation)
Description
Crystallization of aqueous solutions of equimolar quantities of NH4ReO4 and M(ReO4)3 with M = Sc and In at room temperature was used to prepare isostructural binary NH4M(ReO4)4 · 4H2O perrhenates. X-ray diffraction study was conducted for them. Tetragonal (sp.gr. P4n2) crystals NH4M(ReO4)4 · 4H2O (M = Sc, In) are characterized respectively by a = 12.439, 12.460, c = 6.114, 6.123 A, Z = 2, dclc = 3.997, 4.199 g/cm3. M3+ and NH4+ ions, forming the ordered motive of white tin and characterized by eightfold coordination by oxygen, are bonded into frame through bridge ReO4 tetrahedrons and water molecules. 11 refs.; 2 figs.; 4 tabs
Additional details
Additional titles
- Original title (Russian)
- Синтез и кристаллическая структура тетрагидратов двойных перренатов аммония с индием и скандием
Publishing Information
- Journal Title
- Zhurnal Neorganicheskoj Khimii
- Journal Volume
- 41
- Journal Issue
- 4
- Journal Page Range
- p. 549-553.
- ISSN
- 0044-457X
- CODEN
- ZNOKAQ
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 28011850
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMMONIUM COMPOUNDS; BOND ANGLE; BOND LENGTHS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COORDINATION NUMBER; INDIUM COMPOUNDS; LATTICE PARAMETERS; PERRHENATES; SCANDIUM COMPOUNDS; SPACE GROUPS; TEMPERATURE RANGE 0273-0400 K; TETRAGONAL LATTICES
- Descriptors DEC
- CRYSTAL LATTICES; CRYSTAL STRUCTURE; OXYGEN COMPOUNDS; RHENIUM COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS