Published May 8, 2008 | Version v1
Journal article

On the structure and twinning of PtAl4

  • 1. Laboratory of Inorganic Chemistry, ETH-Zurich, Wolfgang-Pauli-Strasse 10, CH-8093 Zurich (Switzerland)
  • 2. Institut Laue Langevin, 6, rue Jules Horowitz, BP156, F-38042 Grenoble Cedex 9 (France)
  • 3. Kantstrasse 1, D-71691 Freiberg (Germany)
  • 4. Collegium Helveticum, Common Institution of the University of Zurich and ETH Zurich, ETH Center/STW, CH-8092 Zurich (Switzerland)

Description

The crystal structure of PtAl4 was determined from synchrotron data (λ = 0.5608 A) of a twinned crystal. PtAl4 crystallizes in the trigonal space group P3c1 (no. 158). The lattice constants are a = 13.077(1) A and b = 9.6342(7) A. The crystal structure represents a new structure type (Pearson symbol hP90) and consists of layers of edge and face sharing Al10-polyhedra, centered by Pt-atoms. The polyhedra layers are stacked along the crystallographic c-axis and are connected by common corners. Two out of 14 Al-positions show positional disorder and occupational deficiencies

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jallcom.2007.01.161

Additional details

Identifiers

DOI
10.1016/j.jallcom.2007.01.161;
PII
S0925-8388(07)00359-3;

Publishing Information

Journal Title
Journal of Alloys and Compounds
Journal Volume
455
Journal Issue
1-2
Journal Page Range
p. 130-136
ISSN
0925-8388
CODEN
JALCEU

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.