Published 1976
| Version v1
Book
Thermodynamic functions for complexing of Msub(aq)sup(3+) ions (M = Pu to Fm)
- 1. Paris-11 Univ., 91 - Orsay (France). Div. de Radiochimie
Description
Some coherent values of thermodynamic data for solvent extraction and complexing of Msub(aq)sup(3+) ions (M=Pu3+ to Fm3+) with TTA in benzene or by hydroxyl and citrato ions have been obtained at μ=0.1. Trouble occurs with Pu and Bk whose tetravalent state, highly extracting and complexing, disturbs the behaviour of Pu(III) and Bk(III). In the range 10-400C data show that the tetrad effect and formation of inner sphere complexes would be expected. (Auth.)
Additional details
Publishing Information
- Publisher
- North-Holland.
- Imprint Place
- Amsterdam, The Netherlands
- ISBN
- 0720404037
- Imprint Title
- Transplutonium 1975
- Imprint Pagination
- p. 109-118.
Conference
- Title
- 4. international transplutonium element symposium.
- Dates
- 13 Sep 1975.
- Place
- Baden Baden, F.R. Germany.
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- Netherlands
- INIS RN
- 7270254
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- AMERICIUM COMPLEXES; BERKELIUM COMPLEXES; CALIFORNIUM COMPLEXES; CURIUM COMPLEXES; EINSTEINIUM COMPLEXES; ENTROPY; FERMIUM COMPLEXES; FORMATION FREE ENERGY; FORMATION HEAT; PLUTONIUM COMPLEXES; SOLVENT EXTRACTION
- Descriptors DEC
- ACTINIDE COMPLEXES; COMPLEXES; ENERGY; ENTHALPY; FREE ENERGY; PHYSICAL PROPERTIES; REACTION HEAT; SEPARATION PROCESSES; THERMODYNAMIC PROPERTIES; TRANSURANIUM COMPLEXES