Published April 1989
| Version v1
Journal article
A Moessbauer study on some organometallic compounds containing Fe-Sn-Fe bond
- 1. Nankai Univ., Tianjin, TJ (China). Inst. of Elementoorganic Chemistry
- 2. Nankai Univ., Tianjin, TJ (China). Central Laboratory
Description
The Mossbauer spectra of compounds with general formula [(π-C5O5)Fe-(CO2)]2Sn (X)(Y) were studied. The corresponding parameters showed that the parameters for iron were assentially independent on the nature of X and Y. The alternation of X and Y caused the change in s electron density through the shielding of s electron or the substitutents inductive effect and subsequently caused the change of tin isomer shifts. The fact that X and Y groups had little effect on iron parameters might be a good evidence for the absence of π interaction between Fe and Sn
Additional details
Publishing Information
- Journal Title
- Acta Chimica Sinica
- Journal Volume
- 47
- Journal Issue
- 4
- Series
- Acta Chim. Sin.
- Journal Page Range
- 319-321
- ISSN
- 0567-7351
- CODEN
- HHHPA
INIS
- Country of Publication
- China
- Country of Input or Organization
- China
- INIS RN
- 21052205
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL BONDS; CHEMICAL SHIFT; IRON; MOESSBAUER EFFECT; ORGANOMETALLIC COMPOUNDS; TIN
- Descriptors DEC
- ELEMENTS; METALS; ORGANIC COMPOUNDS; TRANSITION ELEMENTS