Novel decomposition method for zircon
Creators
- 1. Nuclear Materials Authority (NMA), P.O. Box 530, Maadi, Cairo (Egypt)
- 2. Department of Petroleum, Mining, and Metallurgical Engineering, Cairo University (Egypt)
Description
Zircon is one of the most stable chemical compound due to the strong bond between zirconia and silica in its molecule. Therefore, any extraction for zirconium metal or other useful zirconium compounds must start with the breakdown of such bond. The breakdown of zircon using the alkali fusion method is a well-known techniques and can be more favorable than using traditional chlorination breakdown if less drastic reaction conditions have been obtained. For such reason, the presence work study the fusion of zircon with equimolar ratio of KOH and NaOH as an alternative for using NaOH and Na2Co3. The influence of varying experimental conditions on the zircon fusion has been studied. These variables included the amount of alkali used, the temperature of the reaction, and the reaction duration. Using 20% excess of alkali mixture at 550 deg. C with only 60 min reaction time was favorable to get 96% zircon decomposition
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2007.06.032Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2007.06.032;
- PII
- S0925-8388(07)01381-3;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 460
- Journal Issue
- 1-2
- Journal Page Range
- p. 577-580
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40013373
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- CHLORINATION; DECOMPOSITION; EXTRACTION; POTASSIUM HYDROXIDES; SILICA; SODIUM CARBONATES; SODIUM HYDROXIDES; TEMPERATURE RANGE 0400-1000 K; ZIRCON; ZIRCONIUM OXIDES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBON COMPOUNDS; CARBONATES; CHALCOGENIDES; CHEMICAL REACTIONS; HALOGENATION; HYDROGEN COMPOUNDS; HYDROXIDES; MINERALS; OXIDE MINERALS; OXIDES; OXYGEN COMPOUNDS; POTASSIUM COMPOUNDS; SEPARATION PROCESSES; SILICATE MINERALS; SODIUM COMPOUNDS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.