Published July 28, 2008 | Version v1
Journal article

Novel decomposition method for zircon

  • 1. Nuclear Materials Authority (NMA), P.O. Box 530, Maadi, Cairo (Egypt)
  • 2. Department of Petroleum, Mining, and Metallurgical Engineering, Cairo University (Egypt)

Description

Zircon is one of the most stable chemical compound due to the strong bond between zirconia and silica in its molecule. Therefore, any extraction for zirconium metal or other useful zirconium compounds must start with the breakdown of such bond. The breakdown of zircon using the alkali fusion method is a well-known techniques and can be more favorable than using traditional chlorination breakdown if less drastic reaction conditions have been obtained. For such reason, the presence work study the fusion of zircon with equimolar ratio of KOH and NaOH as an alternative for using NaOH and Na2Co3. The influence of varying experimental conditions on the zircon fusion has been studied. These variables included the amount of alkali used, the temperature of the reaction, and the reaction duration. Using 20% excess of alkali mixture at 550 deg. C with only 60 min reaction time was favorable to get 96% zircon decomposition

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jallcom.2007.06.032

Additional details

Identifiers

DOI
10.1016/j.jallcom.2007.06.032;
PII
S0925-8388(07)01381-3;

Publishing Information

Journal Title
Journal of Alloys and Compounds
Journal Volume
460
Journal Issue
1-2
Journal Page Range
p. 577-580
ISSN
0925-8388
CODEN
JALCEU

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.