Published November 1987
| Version v1
Journal article
Reaction between tetraallyluranium (IV) and tributyl phosphate
Creators
Description
Exchange processes in the tetraallyluranium-tributyl phosphate system are studied by 1H NMR technique at temperatures ranging from 00 to -800C. It is shown that in toluene U(C3H5)4 forms with tributyl phosphate a complex of the composition 1:1. Some physicochemical parameters of the reaction U(eta3-C3H5)4 + (C4H9O)3PO reversible U(eta3-C3H5)4 x (C4H9O)3PO are given
Additional details
Publishing Information
- Journal Title
- Sov. Radiochem. (Engl. Transl.)
- Journal Volume
- 29
- Journal Issue
- 2
- Series
- Sov. Radiochem. (Engl. Transl.).
- Journal Page Range
- 137-141
- ISSN
- 0038-576X
- CODEN
- SVRDA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19081728
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- BOUND STATE; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHEMICAL SHIFT; COMPLEXOMETRY; COORDINATION VALENCES; HYDROGEN 1; LIGANDS; NMR SPECTRA; TBP; TEMPERATURE DEPENDENCE; THERMODYNAMICS; TOLUENE; URANIUM COMPLEXES; URANIUM COMPOUNDS
- Descriptors DEC
- ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; AROMATICS; BUTYL PHOSPHATES; COMPLEXES; ESTERS; HYDROCARBONS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORIC ACID ESTERS; REACTION KINETICS; SPECTRA; STABLE ISOTOPES; VALENCE
Optional Information
- Notes
- Translated from Radiokhimiya; 29: No. 2, 150-154(Mar-Apr 1987).