Published August 1990 | Version v1
Journal article Metadata-only

Spectroscopic study of copper (2) ions interaction with [ZMo12O42]8- heteropolyanion

Creators

  • 1. AN SSSR, Novosibirsk (USSR). Inst. Kataliza
  • 2. Moskovskij Gosudarstvennyj Univ., Moscow (USSR)

Description

By the methods of optical, ESR and NMR spectroscopy interaction of Cu2+ ions with [ZMo12O42]8-heteropolyligand (Z4+=Ce, Th, U) has been investigated. Formation in the solution of copper (2) complex (labile in the NMR time scale) with simultaneous preservation of [ZMo12O42]8- ligand structure in the process of complexing is ascertained. It is pointed out that 17O signal broadening in NMR spectra owing to Cu2+ paramagnetism hampers the revealing of ligang structural distortions in the complex

Additional details

Additional titles

Original title (Russian)
Изучение взаимодействия ионов меди (2) с гетерополианионом [ZMo

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
35
Journal Issue
8
Series
Zh. Neorg. Khim.
Journal Page Range
2110-2113
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
22041890
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CERIUM COMPLEXES; CHEMICAL PREPARATION; COPPER COMPLEXES; ELECTRON SPIN RESONANCE; HETEROPOLYANIONS; MOLECULAR STRUCTURE; NMR SPECTRA; OXYGEN COMPOUNDS; THORIUM COMPOUNDS; URANIUM COMPOUNDS
Descriptors DEC
ACTINIDE COMPOUNDS; ANIONS; CHARGED PARTICLES; COMPLEXES; DISPERSIONS; HOMOGENEOUS MIXTURES; IONS; MAGNETIC RESONANCE; MIXTURES; RARE EARTH COMPLEXES; RESONANCE; SOLUTIONS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES