Published September 20, 1987
| Version v1
Journal article
N-phosphorylated ketene S,N-acetals
- 1. All-Union Research Institute of Chemical Means for the Protection of Plants, Moscow (USSR)
Description
The authors investigate the reactions of phosphorisocyanitidic and phosphorisocyanatidothioc esters with organic CH acids and determine that the products, depending on the substituent on the beta-carbon atom, are either ketene S,N-acetals or equilibrium mixtures of these and phosphorylated imino thioesters. IR spectra were determined in chloroform. H 1 and P 31 NMR spectra were determined in deuterated acetone. An analysis of the spectra, including the determination of spin-spin coupling constants, is conducted
Additional details
Publishing Information
- Journal Title
- J. Gen. Chem. USSR (Engl. Transl.)
- Journal Volume
- 57
- Journal Issue
- 4
- Series
- J. Gen. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 681-685
- ISSN
- 0022-1279
- CODEN
- JGCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19081705
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- ACETALS; ACETONE; CHEMICAL SHIFT; COUPLING CONSTANTS; DEUTERIUM COMPOUNDS; ESTERS; HYDROGEN 1; INFRARED SPECTRA; ISOMERIZATION; J-J COUPLING; KETONES; NMR SPECTRA; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SOLVENTS; ORGANIC SULFUR COMPOUNDS; PHOSPHORUS 31; PHOSPHORYLATION; SYNTHESIS
- Descriptors DEC
- CHEMICAL REACTIONS; COUPLING; ETHERS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INTERMEDIATE COUPLING; ISOTOPES; LIGHT NUCLEI; NONAQUEOUS SOLVENTS; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHOSPHORUS ISOTOPES; SOLVENTS; SPECTRA; STABLE ISOTOPES
Optional Information
- Notes
- Translated from Zh. Obshch. Khim.; 57: No. 4, 772-777(Apr 1987).