Published May 1991
| Version v1
Journal article
Hydrazonium tricarboxylatouranylates
- 1. Moskovskij Gosudarstvennyj Univ., Moscow (USSR)
Description
Complexes of N2H5[UO2A3] composition were synthesized in result of interaction of acidified aqueous UO2A2 solutions (A=CH3COO-, C2H5COO-) and hydrazine hydrate. The individual character of prepared complexes was confirmed by the data of elementary, X-ray phase analyses and IR spectroscopy. The structure of prepared compounds was proposed on the basis of IR spectroscopic data. Decomposition of complexes under poly- and isothermal conditions was studied. It is shown that thermolysis of the compounds proceeds in a narrow temperature range. Its mechanism includes several stages, the first of which is Anderson rearrangement
Additional details
Additional titles
- Original title (Russian)
- Трикарбоксилатоуранилаты гидразиния
Publishing Information
- Journal Title
- Zhurnal Neorganicheskoj Khimii
- Journal Volume
- 36
- Journal Issue
- 5
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 1235-1239
- ISSN
- 0044-457X
- CODEN
- ZNOKA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 23016219
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CARBOXYLIC ACID SALTS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COORDINATION NUMBER; HYDRAZINE; INFRARED SPECTRA; MOLECULAR STRUCTURE; PYROLYSIS; PYROLYSIS PRODUCTS; URANYL COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; DISPERSIONS; HOMOGENEOUS MIXTURES; MIXTURES; SOLUTIONS; SPECTRA; SYNTHESIS; URANIUM COMPLEXES