Published June 2014 | Version v1
Journal article Metadata-only

Between oxoborate and nitridoborate: the oxonitridoborate oxide La3(OBN2)O2

Creators

  • 1. Fachbereich Chemieingenieurwesen, Fachhochschule Muenster, Steinfurt (Germany)
  • 2. Abteilung fuer Festkoerperchemie und Theoretische Anorganische Chemie, Institut fuer Anorganische Chemie, Universitaet Tuebingen (Germany)

Description

The new compound La3(OBN2)O2 was prepared by a solid state reaction of LaOCl and Li3(BN2) at 1200 C in a fused niobium ampoule. A single crystal structure refinement [Pnma, Z = 4, a = 1269.8(2) pm, b = 368.94(5) pm, c = 1101.1(2) pm] indicates the presence of a planar (OBN2)5- ion, which is structurally related to the (BN3)6- ion. The arrangement of atoms in the structure corresponds to a slightly modified structure of Ca3(CBN)Cl2 [Pnma, Z = 4, a = 1386.7(9) pm, b = 384.7(3) pm, c = 1124.7(6) pm]. (Copyright copyright 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/zaac.201400045

Additional details

Identifiers

DOI
10.1002/zaac.201400045;

Publishing Information

Journal Title
Zeitschrift fuer Anorganische und Allgemeine Chemie (1950)
Journal Volume
640
Journal Issue
7
Journal Page Range
p. 1275-1279
ISSN
0044-2313
CODEN
ZAACAB

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48053765
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTAL STRUCTURE; LANTHANUM BORIDES; LANTHANUM NITRIDES; LANTHANUM OXIDES; LATTICE PARAMETERS; MONOCRYSTALS; SYNTHESIS
Descriptors DEC
BORIDES; BORON COMPOUNDS; CHALCOGENIDES; CRYSTALS; LANTHANUM COMPOUNDS; NITRIDES; NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PNICTIDES; RARE EARTH COMPOUNDS

Optional Information

Notes
With 4 figs., 3 tabs., 24 refs.