Published January 7, 2009
| Version v1
Journal article
Hydrogenation of HoCu: Hydride formation and magnetic properties
- 1. Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)
- 2. Tata Institute of Fundamental Research, Colaba, Mumbai 400005 (India)
Description
The intermetallic compound HoCu is hydrogenated to form a composition HoCuH3. Magnetic properties of the hydride have been studied by magnetization, low temperature heat capacity and electrical resistivity measurements. While HoCu is antiferromagnetic with a Neel temperature of ∼27 K, the hydride does not show any indication of homogeneous long range magnetic ordering down to 1.6 K. The magnetization and the heat capacity measurements can be reconciled to a spin glass kind of behavior for the hydride. An upturn in the resistivity of HoCuH3 below 30 K may imply the presence of disorder, which is necessary for inducing spin glass behavior
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2007.11.114Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2007.11.114;
- PII
- S0925-8388(07)02248-7;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 467
- Journal Issue
- 1-2
- Journal Page Range
- p. 10-13
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40050042
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- ANTIFERROMAGNETISM; COPPER COMPOUNDS; ELECTRIC CONDUCTIVITY; HOLMIUM COMPOUNDS; HYDRIDES; MAGNETIC PROPERTIES; MAGNETIZATION; NEEL TEMPERATURE; SPECIFIC HEAT; SPIN GLASS STATE; TEMPERATURE RANGE 0000-0013 K; TEMPERATURE RANGE 0013-0065 K; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; DIFFRACTION; ELECTRICAL PROPERTIES; HYDROGEN COMPOUNDS; MAGNETISM; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; SCATTERING; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION TEMPERATURE
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.