Published January 7, 2009 | Version v1
Journal article

Hydrogenation of HoCu: Hydride formation and magnetic properties

  • 1. Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)
  • 2. Tata Institute of Fundamental Research, Colaba, Mumbai 400005 (India)

Description

The intermetallic compound HoCu is hydrogenated to form a composition HoCuH3. Magnetic properties of the hydride have been studied by magnetization, low temperature heat capacity and electrical resistivity measurements. While HoCu is antiferromagnetic with a Neel temperature of ∼27 K, the hydride does not show any indication of homogeneous long range magnetic ordering down to 1.6 K. The magnetization and the heat capacity measurements can be reconciled to a spin glass kind of behavior for the hydride. An upturn in the resistivity of HoCuH3 below 30 K may imply the presence of disorder, which is necessary for inducing spin glass behavior

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jallcom.2007.11.114

Additional details

Identifiers

DOI
10.1016/j.jallcom.2007.11.114;
PII
S0925-8388(07)02248-7;

Publishing Information

Journal Title
Journal of Alloys and Compounds
Journal Volume
467
Journal Issue
1-2
Journal Page Range
p. 10-13
ISSN
0925-8388
CODEN
JALCEU

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.