Published 1976 | Version v1
Report

Possible alcohol multimers involved in electron solvation

  • 1. Australian Atomic Energy Commission Research Establishment, Lucas Heights. Isotope Div.

Description

Pulse radiolysis studies of the yield of solvated electrons as a function of concentration of alcohol in alkane mixtures indicated that the electrons were stabilised in a preformed or partially preformed trap. The temperature effects on the yield and on the Kirkwood correlation coefficient (based on the contribution of additional alcohol molecule dipoles to the dielectric constant of the medium) showed that these traps were almost certainly alcohol multimeric species formed by hydrogen bonding. (author)

Additional details

Publishing Information

Imprint Title
8th AINSE radiation chemistry conference 8th-10th November 1976
Imprint Pagination
p. 27.
Report number
INIS-mf--3357

Conference

Title
8. AINSE radiation chemistry conference.
Dates
8 Nov 1976.
Place
Lucas Heights, Australia.

INIS

Country of Publication
Australia
Country of Input or Organization
Australia
INIS RN
8298472
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Conference, No Abstract
Descriptors DEI
ALCOHOLS; MOLECULAR STRUCTURE; POLYMERS; PULSED IRRADIATION; RADIOLYSIS; SOLVATED ELECTRONS
Descriptors DEC
CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTRONS; ELEMENTARY PARTICLES; FERMIONS; HYDROXY COMPOUNDS; IRRADIATION; LEPTONS; ORGANIC COMPOUNDS; RADIATION EFFECTS

Optional Information

Notes
Abstract only.