Published 1981 | Version v1
Journal article Metadata-only

The cation of hexamethyldistannane generated by radiolysis: an E.S.R. study

Creators

  • 1. Leicester Univ. (UK). Dept. of Chemistry

Description

Analysis of the Sn hyperfine tensor components for (Me3Sn.SnMe3)+ generated by radiolysis of hexamethyldistannane in fluorotrichloromethane at 77 K shows that the metal-metal orbital is largely 4psub(z) + 4psub(z), the 4s contribution being negligible. (author)

Additional details

Publishing Information

Journal Title
J. Chem. Soc. (London), Chem. Commun.
Journal Issue
no.24
Series
J. Chem. Soc. (London), Chem. Commun.
ISSN
0022-4936

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
13661206
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ALKANES; CATIONS; ELECTRON SPIN RESONANCE; ELECTRONIC STRUCTURE; GAMMA RADIATION; HYPERFINE STRUCTURE; LOW TEMPERATURE; MOLECULAR STRUCTURE; ORGANIC SOLVENTS; ORGANOMETALLIC COMPOUNDS; RADICALS; RADIOLYSIS; SPECTRA; TIN COMPOUNDS
Descriptors DEC
CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; HYDROCARBONS; IONIZING RADIATIONS; IONS; MAGNETIC RESONANCE; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RESONANCE; SOLVENTS