Published November 10, 1987
| Version v1
Journal article
Conjugation of monoalkylamino and dialkylamino groups with the phenyl ring
- 1. Institute of Physical Organic Chemistry and Coal Chemistry, Donetsk (USSR)
Description
The σ/sub R//sup 0/ constants of N-alkylamino and N,N-dialkylamino groups (alkyl + CH3, C2H5, C3H7, iso-C3H2, C4H9 and C6H5CH2) relative to the integral intensities of the IR ring stretching bands are calculated. The capacity of the amino group to conjugate with the phenyl ring π-system is enhanced upon the introduction of alkyl groups at the nitrogen atom of this group. The lowest σ/sub R//sup 0/ constant was found for the diisopropylamino group among the dialkylamino groups
Additional details
Publishing Information
- Journal Title
- J. Org. Chem. USSR (Engl. Transl.)
- Journal Volume
- 23
- Journal Issue
- 6
- Series
- J. Org. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 1109-1111
- ISSN
- 0022-3271
- CODEN
- JOCYA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19087111
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- ALKYLATION; AMINES; ATOMIC MODELS; CONFIGURATION INTERACTION; ELECTRON TRANSFER; ELECTRONIC STRUCTURE; HYBRIDIZATION; INFRARED SPECTRA; ISOMERIZATION; MOLECULAR MODELS; MOLECULAR STRUCTURE; SPIN; STRUCTURAL CHEMICAL ANALYSIS; VIBRATIONAL STATES
- Descriptors DEC
- ANGULAR MOMENTUM; CHEMICAL REACTIONS; ENERGY LEVELS; EXCITED STATES; MATHEMATICAL MODELS; ORGANIC COMPOUNDS; PARTICLE PROPERTIES; SPECTRA
Optional Information
- Notes
- Translated from Zh. Org. Khim.; 23: No. 6, 1228-1230(Jun 1987).