Published February 13, 1986
| Version v1
Journal article
Absolute rate constant for the reaction SiH2 + D2
Description
An absolute rate constant for the reaction of silylene with molecular deuterium at room temperature has been measured by laser resonance absorption flash kinetic spectroscopy. The rate constant is four orders of magnitude larger than previous data suggest and provides experimental support for recent ab initio theoretical results. 44 references, 5 figures
Additional details
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 90
- Journal Issue
- 4
- Series
- J. Phys. Chem.
- Journal Page Range
- 555-557
- ISSN
- 0022-3654
- CODEN
- JPCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 17076410
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; CHEMICAL LASERS; CHEMICAL REACTION KINETICS; DEUTERIUM; DYE LASERS; EXPERIMENTAL DATA; PULSE TECHNIQUES; RESONANCE ABSORPTION; SILANES; VISIBLE SPECTRA
- Descriptors DEC
- ABSORPTION; AMPLIFIERS; DATA; EQUIPMENT; HYDRIDES; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INFORMATION; ISOTOPES; KINETICS; LASERS; LIGHT NUCLEI; NUCLEI; NUMERICAL DATA; ODD-ODD NUCLEI; REACTION KINETICS; SILICON COMPOUNDS; SPECTRA; SPECTROSCOPY; STABLE ISOTOPES