Published March 1, 2011 | Version v1
Journal article

Crystal growth, stability and photoluminescence studies of tetra aqua diglycine magnesium (II) hexa aqua magnesium (II) bis sulfate crystal

  • 1. Centre for Crystal Growth, SSN College of Engineering, Kalavakkam, Tamilnadu 603 110 (India)

Description

Single crystals of tetra aqua diglycine magnesium (II) hexa aqua magnesium (II) bis sulfate have been grown from saturated aqueous solution by slow evaporation solution growth technique. The solubility of the title compound in water at various temperatures has been determined. Single-crystal X-ray diffraction analyses reveal that the title compound crystallizes in triclinic system with space group P1-bar . Fourier transform infrared spectral analyses confirm the presence of functional groups in the grown crystal. The thermal stability of the grown crystal has been investigated by thermogravimetric and differential scanning calorimetric analysis. It indicates that the material is stable upto 100 oC. The crystalline perfection of the grown crystal has been evaluated by high-resolution X-ray diffraction technique. Vickers microhardness measurements indicate the mechanical strength of the grown crystal. Photoluminescence of the grown crystal has been investigated and it reveals that the crystal has blue-violet fluorescence emission.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.physb.2010.12.075

Additional details

Identifiers

DOI
10.1016/j.physb.2010.12.075;
PII
S0921-4526(11)00010-X;

Publishing Information

Journal Title
Physica. B, Condensed Matter
Journal Volume
406
Journal Issue
5
Journal Page Range
p. 1169-1172
ISSN
0921-4526
CODEN
PHYBE3

Optional Information

Copyright
Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.