Crystal growth, stability and photoluminescence studies of tetra aqua diglycine magnesium (II) hexa aqua magnesium (II) bis sulfate crystal
Creators
- 1. Centre for Crystal Growth, SSN College of Engineering, Kalavakkam, Tamilnadu 603 110 (India)
Description
Single crystals of tetra aqua diglycine magnesium (II) hexa aqua magnesium (II) bis sulfate have been grown from saturated aqueous solution by slow evaporation solution growth technique. The solubility of the title compound in water at various temperatures has been determined. Single-crystal X-ray diffraction analyses reveal that the title compound crystallizes in triclinic system with space group P1-bar . Fourier transform infrared spectral analyses confirm the presence of functional groups in the grown crystal. The thermal stability of the grown crystal has been investigated by thermogravimetric and differential scanning calorimetric analysis. It indicates that the material is stable upto 100 oC. The crystalline perfection of the grown crystal has been evaluated by high-resolution X-ray diffraction technique. Vickers microhardness measurements indicate the mechanical strength of the grown crystal. Photoluminescence of the grown crystal has been investigated and it reveals that the crystal has blue-violet fluorescence emission.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.physb.2010.12.075Additional details
Identifiers
- DOI
- 10.1016/j.physb.2010.12.075;
- PII
- S0921-4526(11)00010-X;
Publishing Information
- Journal Title
- Physica. B, Condensed Matter
- Journal Volume
- 406
- Journal Issue
- 5
- Journal Page Range
- p. 1169-1172
- ISSN
- 0921-4526
- CODEN
- PHYBE3
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 42075685
- Subject category
- S36: MATERIALS SCIENCE; S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- ABSORPTION; AQUEOUS SOLUTIONS; CALORIMETRY; CRYSTAL GROWTH; EVAPORATION; FLUORESCENCE; MAGNESIUM COMPOUNDS; MICROHARDNESS; MONOCRYSTALS; PHOTOLUMINESCENCE; RESOLUTION; SPACE GROUPS; STABILITY; SULFATES; THERMAL GRAVIMETRIC ANALYSIS; TRICLINIC LATTICES; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; CHEMICAL ANALYSIS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; DISPERSIONS; EMISSION; GRAVIMETRIC ANALYSIS; HARDNESS; HOMOGENEOUS MIXTURES; LUMINESCENCE; MECHANICAL PROPERTIES; MIXTURES; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; PHOTON EMISSION; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SOLUTIONS; SORPTION; SULFUR COMPOUNDS; SYMMETRY GROUPS; THERMAL ANALYSIS
Optional Information
- Copyright
- Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.