Published June 1984 | Version v1
Journal article Metadata-only

Study of low-high spin transition on Co3, Ru3, Rh3 atoms in LaAlO3 lattice

Creators

  • 1. Leningradskij Gosudarstvennyj Univ. (USSR)
  • 2. Syktyvkarskij Gosudarstvennyj Univ. (USSR)

Description

According to the data on temperature dependence of effective magnetic momentum of diluted solid solutions LaMesub(x)Alsub(1-x)Osub(3) (Me--Co, Ru, Rh; x <= 0.1) the energy of transition from low-spin to the high-spin state for Co3, Ru3, Rh3 atoms in diamagnetic matrix of LaAlO3 is calculated. It is shown that inspite of considerable splitting in crystal field of the basic state, spin-orbital interaction results in comparatively low energy of the transition low-high spin

Additional details

Additional titles

Original title (Russian)
Исследование перехода низкий-высокий спин на атомах Cо

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
29
Journal Issue
6
Series
Zh. Neorg. Khim.
Journal Page Range
1387-1390
ISSN
0044-457X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
16016939
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALUMINIUM OXIDES; CRYSTAL FIELD; ENERGY-LEVEL TRANSITIONS; HIGH SPIN STATES; L-S COUPLING; LANTHANUM OXIDES; LOW TEMPERATURE; MAGNETIC MOMENTS; MEDIUM TEMPERATURE; RUTHENIUM OXIDES; SOLID SOLUTIONS; TEMPERATURE DEPENDENCE
Descriptors DEC
ALUMINIUM COMPOUNDS; CHALCOGENIDES; COUPLING; DISPERSIONS; ENERGY LEVELS; HOMOGENEOUS MIXTURES; INTERMEDIATE COUPLING; LANTHANUM COMPOUNDS; MIXTURES; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; RUTHENIUM COMPOUNDS; SOLUTIONS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).