Published January 1, 1991
| Version v1
Journal article
A pyrolysis jet spectroscopic study of the rotationally resolved electronic spectrum of dichlorocarbene
Creators
- 1. Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506 (USA)
- 2. Quantum Electronics Laboratory, Institute of Physics, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, (Poland)
Description
The rotationally resolved, gas phase vibronic spectrum of dichlorocarbene has been recorded using the technique of pyrolysis jet spectroscopy. The rovibronic analysis has established the band origin of the A 1B1--X 1A1 electronic transition to be at 17 255.67 cm-1. The observed vibrational frequencies in the ground and excited states are very close to published values from matrix isolation data. The excited state structure has a 131.4 degree ClCCl angle and a 1.652 A CCl bond length
Additional details
Publishing Information
- Journal Title
- Journal of Chemical Physics
- Journal Volume
- 94
- Journal Issue
- 1
- Series
- J. Chem. Phys.
- Journal Page Range
- 1-10
- ISSN
- 0021-9606
- CODEN
- JCPSA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 22039270
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; BOND LENGTHS; CARBENES; CHEMICAL ANALYSIS; EXCITED STATES; ORGANIC CHLORINE COMPOUNDS; PYROLYSIS; REACTION INTERMEDIATES; ROTATIONAL STATES; VIBRATIONAL STATES
- Descriptors DEC
- CHEMICAL REACTIONS; DECOMPOSITION; ENERGY LEVELS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADICALS; SPECTRA