Published March 6, 1998 | Version v1
Journal article

A thermodynamic modelling of the Co-Ce system

  • 1. Beijing Univ. of Science and Technology, BJ (China). Dept. of Materials Science and Engineering

Description

The phase diagram and thermodynamic data of the Co-Ce system have been critically assessed by means of the computer programs THERMO-CALC. Special attention is paid to the Co5Ce and Co17Ce2 compounds. The Co5Ce and Co17Ce2 compounds are described as stoichiometric compounds in the first treatment; in the second treatment, they are described as one phase denoted δ, and a three-sublattice model Co15Ce2(Ce,Co2), based on the crystal structure, is used to model the δ phase. The other phases are modelled with the Redlich-Kister formula [liquid, fcc, bcc, hcp] or as stoichiometric compounds [Co19Ce5, Co7Ce2, Co3Ce, Co2Ce, Co11Ce24]. Good agreement is obtained between the calculations and experimental results. (orig.)

Additional details

Publishing Information

Journal Title
Journal of Alloys and Compounds
Journal Volume
267
Journal Issue
1-2
Journal Page Range
p. 121-127
ISSN
0925-8388
CODEN
JALCEU

INIS

Country of Publication
Netherlands
Country of Input or Organization
Switzerland
INIS RN
29038294
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CALCULATION METHODS; CERIUM ALLOYS; COBALT ALLOYS; PHASE DIAGRAMS; STOICHIOMETRY; THERMODYNAMIC PROPERTIES
Descriptors DEC
ALLOYS; DIAGRAMS; INFORMATION; PHYSICAL PROPERTIES; RARE EARTH ALLOYS; TRANSITION ELEMENT ALLOYS

Optional Information

Notes
22 refs.