Published September 1994 | Version v1
Journal article Metadata-only

Crystal structure of (BOPDT-TTF)+I5-: C10H8O2I5S8

Creators

  • 1. Permskij Gosudarstvennyj Univ., Perm (Russian Federation)

Description

Crystal structure of a new conducting salt -bis(oxapropylenedithiotetrathiafulvalene)pentaiodide has been studied: sp.gr. C2/c; a=20.253(5), b=8.498(2), c=16.116(3) A, β=117.66(1) deg, Z=4, d=2.84 g/cm3. The structure contains two different types of iodine, linear anion is I3, located in inversion centre, with I-I distances = 2.964(1) A and I2 pairs with I-I distances = 2.764(1) A. The shortest I-I distance between I3 linear anions and I2 couples is 3.383(1) A. At 300 K the salt is a semiconductor (2.5 · 10-5 S x cm-1). 6 refs.; 3 figs.; 2 tabs

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура (BOPDT-TTF)

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
35
Journal Issue
5
Journal Page Range
p. 193-197.
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27055368
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTAL LATTICES; DENSITY; ELECTRIC CONDUCTIVITY; HETEROCYCLIC COMPOUNDS; INTERATOMIC DISTANCES; IODIDES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; ORGANIC SULFUR COMPOUNDS; SEMICONDUCTOR MATERIALS; SPACE GROUPS
Descriptors DEC
CRYSTAL STRUCTURE; DISTANCE; ELECTRICAL PROPERTIES; HALIDES; HALOGEN COMPOUNDS; IODINE COMPOUNDS; MATERIALS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS