Published July 2021 | Version v1
Journal article Metadata-only

Adsorptive characteristics of some metal ions on chitosan/zirconium phosphate/silica decorated graphene oxide

Creators

  • 1. Egyptian Atomic Energy Authority (EAEA), Cairo (Egypt). Hot Laboratories and Waste Management Center
  • 2. Menoufia University, Shebin El-Kom (Egypt). Chemistry Department

Description

Graphene oxide/chitosan/zirconiumphosphate/silicate (GO/CS/ZrP/Si) as a novel nano-composite has highly adsorption of 134Cs, 60Co, 152,154Eu and 160Tb. The GO/CS/ZrP/Si has better adsorption of 152,154Eu and 160Tb. A comparison of the adsorption kinetics and isotherms were analyzed using different models. The adsorption data was fitting with the pseudo second-order and the Langmuir isotherm. The changes in Gibbs free energy ΔGo), enthalpy (ΔHo), and entropy (ΔSo) have been calculated. Selective adsorption of lanthanide ions from monazite solution was achieved. The break through capacities of Sm3+, La3+, Eu3+ and Tb3+ on GO/CS/ZrP/Si were found as 14.5, 13.0, 14.8 and 14.9 mg/g respectively. (author)

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
329
Journal Issue
1
Journal Page Range
p. 191-211
ISSN
0236-5731
CODEN
JRNCDM

INIS

Country of Publication
Hungary
Country of Input or Organization
Hungary
INIS RN
52075596
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADSORPTION; GRAPHENE; ISOTHERMS; KINETICS; POLYSACCHARIDES; RADIOACTIVE WASTES; ZIRCONIUM PHOSPHATES
Descriptors DEC
CARBOHYDRATES; CARBON; ELEMENTS; MATERIALS; NONMETALS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; RADIOACTIVE MATERIALS; SACCHARIDES; SORPTION; TRANSITION ELEMENT COMPOUNDS; WASTES; ZIRCONIUM COMPOUNDS

Optional Information

Notes
73 refs.