Published April 1995
| Version v1
Journal article
Structure of Co(2), Ni(2) and VO(2) complexes with 4-phenylthiosemicarbaziddiacetic acid
Creators
- 1. AN Moldavskoj SSR, Kishinev (Moldova, Republic of). Inst. Khimii
- 2. AN Moldavskoj SSR, Kishinev (Moldova, Republic of). Inst. Prikladnoj Fiziki
Description
Structure of complex compounds VO(2)(3) with 4-phyenylthiosemicarbaziddiacetic acid is determined through X-ray diffraction method. Monocrystal compounds are monoclinic, sp.gr. P21/n (a=6.703(2), b=12.470(7), c=1695(6) A, γ=95.10(4) deg). The organic molecule in the complexes is expressed in form of twofold deprotonated tetradentate, ligand joining to metal according to the tripod type with application of donor atoms S, N, O, O and forming three metallocycles. The coordination surrounding of the central atom is supplemented by one oxygen vanadyl atom and one water molecule. 17 refs.; 4 figs.; 5 tabs
Additional details
Additional titles
- Original title (Russian)
- Stroenie kompleksnykh soedinenij Co(2), Ni(2) i VO(2) s 4-feniltiosemikarbaziddiuksusnoj kislotoj
Publishing Information
- Journal Title
- Koordinatsionnaya Khimiya
- Journal Volume
- 21
- Journal Issue
- 4
- Journal Page Range
- p. 341-348.
- ISSN
- 0132-344X
- CODEN
- KOKHDC
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 26075672
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AROMATICS; BOND ANGLE; BOND LENGTHS; CHEMICAL BONDS; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; ORGANIC SULFUR COMPOUNDS; SEMICARBAZIDES; SPACE GROUPS; VANADIUM COMPLEXES
- Descriptors DEC
- CARBONIC ACID DERIVATIVES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES