Published July 1997
| Version v1
Journal article
Investigation of electronic and spatial structure of cadmium(2) dialkyldithiocarbamate molecules in nonaqueous media
Creators
- 1. Inst. Neorganicheskoj Khimii SO RAN, Novosibirsk (Russian Federation)
Description
CdK EXAFS and 113Cd NMR spectra for solutions of cadmium dialkyldithiocrbomates in organic solvents with various donor number (tributylphosphine, methylenechloride, benzene, dibutylsulfide, pyridine, dimethylsulforxide), and also for a number of model compounds, are measured. The parameters of the cadmium atoms surrounding for complex forms in solutions are determined. Models for spatial structures of complex forms, formed in the metal chelate - nonaqueous solvent systems, are proposed
Additional details
Additional titles
- Original title (Russian)
- Issledovanie ehlektronnogo i prostranstvennogo stroeniya molekul dialkilditiokarbamatov kadmiya(2) v nevodnykh sredakh
Publishing Information
- Journal Title
- Zhurnal Strukturnoj Khimii
- Journal Volume
- 38
- Journal Issue
- 4
- Journal Page Range
- p. 723-731
- ISSN
- 0136-7463
- CODEN
- ZSTKAI
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 29054502
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CADMIUM COMPLEXES; CARBAMATES; CHELATES; CHEMICAL SHIFT; CONCENTRATION RATIO; ELECTRONIC STRUCTURE; INTERATOMIC DISTANCES; MOLECULAR STRUCTURE; NMR SPECTRA; ORGANIC SOLVENTS; ORGANIC SULFUR COMPOUNDS; SOLVATION
- Descriptors DEC
- CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID SALTS; COMPLEXES; DISTANCE; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SOLVENTS; SPECTRA
Optional Information
- Notes
- 25 refs.; 2 tabs.; 2 figs.