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[en] Aquatic or land-based plastic pollution has raised serious concerns for ecosystems, and especially human and animal health worldwide. A variety of legislative instruments were developed to control, reduce, and manage the usage of plastics in day-to-day life to minimize the adverse outcomes brought by sending these plastic to landfill. Existing legislation heavily embraces levies, bans, and voluntary efforts through “reduce and reuse campaigns.” Thus, the present review highlights the pros and cons of the existing legislation and its implementation. It also assesses the need for the improvement of plastic legislation to better consider environmental and human health impacts. The paper proposes new efficient management strategies to aid in the development of plastic legislation which prevents increase of plastic pollution worldwide, the potential challenges that would arise from its implementation, and the mechanisms for overcoming these challenges. The paper proposes a conventional management strategy based on the current plastic management and legislation. It aims to improve the feasibility and effectiveness of the implementation of future plastic policies.
[en] Highlights: • In vitro assessment of B[a]P in contaminated soils using 4 different methods. • An exponential kinetic model fits well with the extractability data. • Fitting parameter and "1"4C residue correlates with key soil properties. • Fractionation of B[a]P was obtained based on extractability by extractants. - Abstract: Changes in benzo[a]pyrene (B[a]P) extractability over 160 days ageing in four contrasting soils varying in organic matter content and clay mineralogy were investigated using dichloromethane: acetone 1:1 (DCM/Ace), 60 mM hydroxypropyl-β-cyclodextrin (HPCD) solution, 1-butanol (BuOH) and Milli-Q water. The B[a]P extractability by the four methods decreased with ageing and a first-order exponential model could be used to describe the kinetics of release. Correlation of the kinetic rate constant with major soil properties showed a significant effect of clay and sand contents and pore volume fraction (<6 nm) on sequestration of the desorbable fraction (by HPCD) and the water-extractable fraction. Analysis of "1"4C-B[a]P in soils after ageing showed a limited loss of B[a]P via degradation. Fractionation of B[a]P pools associated with the soil matrix was analysed according to extractability of B[a]P by the different extraction methods. A summary of the different fractions is proposed for the illustration of the effect of ageing on different B[a]P-bound fractions in soils. This study provides a better understanding of the B[a]P ageing process associated with different fractions and also emphasises the extraction capacity of the different methods employed