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AbstractAbstract
No abstract available
Original Title
Rastvorimost' iodistogo kadmiya v vode pri vysokikh davleniyakh
Primary Subject
Source
Deposited article; for English translation see the journal Russ. J. Phys. Chem.
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Journal Article
Journal
Zhurnal Fizicheskoj Khimii; v. 46(8); p. 2160-2161
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Wang, Hongxin; Yoda, Yoshitaka; Kamali, Saeed; Zhou, Zhao-Hui; Cramer, Stephen P., E-mail: hxwang2@lbl.gov, E-mail: hxwang2@lbl.gov2012
AbstractAbstract
[en] The real sample temperatures during the nuclear resonant vibrational spectroscopy on biological samples have been assessed and significantly reduced (116 → 52 K) by improving the sample-loading procedures. There are several practical and intertangled issues which make the experiments of nuclear resonant vibrational spectroscopy (NRVS) on biological samples difficult to perform. The sample temperature is one of the most important issues. In NRVS the real sample temperatures can be very different from the readings on the temperature sensors. In this study the following have been performed: (i) citing and analyzing various existing NRVS data to assess the real sample temperatures during the NRVS measurements and to understand their trends with the samples’ loading conditions; (ii) designing several NRVS measurements with (Et_4N)[FeCl_4] to verify these trends; and (iii) proposing a new sample-loading procedure to achieve significantly lower real sample temperatures and to balance among the intertangled experimental issues in biological NRVS measurements
Primary Subject
Source
S0909049512001380; Available from http://dx.doi.org/10.1107/S0909049512001380; Available from http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3284345; PMCID: PMC3284345; PMID: 22338688; PUBLISHER-ID: kt5030; OAI: oai:pubmedcentral.nih.gov:3284345; Copyright (c) Hongxin Wang et al. 2012; This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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AbstractAbstract
No abstract available
Original Title
Magnitoostsillyatsionnyj ehffekt pogloshcheniya v SbJ3
Source
Published in summary form only. For English translation see the journal Sov. Phys. J.
Record Type
Journal Article
Journal
Izvestiya Vysshikh Uchebnykh Zavedenij, Fizika; (no.2); p. 127-129
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AbstractAbstract
No abstract available
Original Title
Sur l'activite glacogene de particules d'AgI irradiees aux rayons γ
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Journal Article
Journal
Journal de Recherches Atmospheriques; v. 5(3); p. 127-131
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AbstractAbstract
No abstract available
Original Title
Kristallizatsiya monoiodida medi CuI v gidrotermal'nykh usloviyakh
Source
published in summary form only.
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Journal Article
Journal
Kristallografiya; v. 17(no.1); p. 230
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AbstractAbstract
No abstract available
Original Title
Vliyanie odnoosnoj deformatsii na spektr pogloshcheniya kristallov iodistogo vismuta
Source
For English translation see the journal Sov. Phys. - Solid State.
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Journal Article
Journal
Fizika Tverdogo Tela; v. 14(11); p. 3252-3255
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Ganguly, Sumit; Thomas, Kolle E.; Ghosh, Abhik
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). Funding organisation: USDOE Office of Science - SC, Biological and Environmental Research (BER) (SC-23) (United States); Research Council of Norway (Norway); National Institutes of Health (NIH) (United States)2017
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). Funding organisation: USDOE Office of Science - SC, Biological and Environmental Research (BER) (SC-23) (United States); Research Council of Norway (Norway); National Institutes of Health (NIH) (United States)2017
AbstractAbstract
[en] Two new series of iron meso-tris(para-X-phenyl)corrole (TpXPC) complexes, Fe[TpXPC]Ph and Fe[TpXPC]Tol, in which X=CF3, H, Me, and OMe, and Tol=p-methylphenyl (p-tolyl), have been synthesized, allowing a multitechnique electronic–structural comparison with the corresponding FeCl, FeNO, and Fe2(μ-O) TpXPC derivatives. Optical spectroscopy revealed that the Soret maxima of the FePh and FeTol series are insensitive to the phenyl para substituent, consistent with the presumed innocence of the corrole ligand in these compounds. Accordingly, we may be increasingly confident in the ability of the substituent effect criterion to serve as a probe of corrole noninnocence. Furthermore, four complexes—Fe[TPC]Cl, Fe[TPC](NO), {Fe[TPC]}2O, and Fe[TPC]Ph—were selected for a detailed XANES investigation of the question of ligand noninnocence. The intensity-weighted average energy (IWAE) positions were found to exhibit rather modest variations (0.8 eV over the series of corroles). The integrated Fe-K pre-edge intensities, on the other hand, vary considerably, with a 2.5 fold increase for Fe[TPC]Ph relative to Fe[TPC]Cl and Fe[TPC](NO). Given the approximately C4v local symmetry of the Fe in all the complexes, the large increase in intensity for Fe[TPC]Ph may be attributed to a higher number of 3d holes, consistent with an expected FeIV-like description, in contrast to Fe[TPC]Cl and Fe[TPC](NO), in which the Fe is thought to be FeIII-like. In conclusion, these results afford strong validation of XANES as a probe of ligand noninnocence in metallocorroles. Electrochemical redox potentials, on the other hand, were found not to afford a simple probe of ligand noninnocence in Fe corroles.
Primary Subject
Source
OSTIID--1425580; AC02-76SF00515; P41GM103393; Available from https://www.osti.gov/pages/biblio/1425580; DOE Accepted Manuscript full text, or the publishers Best Available Version will be available free of charge after the embargo period; Country of input: United States
Record Type
Journal Article
Journal
Chemistry (Weinheim); ISSN 0947-6539;
; v. 23(60); p. 15098-15106

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External URLExternal URL
AbstractAbstract
[en] Second harmonic generation (SHG) from a short-period structure composed of alternating antiferromagnetic (AF) and ionic-crystal layers is investigated, where the generated harmonic waves are situated in the far-infrared range and attributed to the magnetically nonlinear interaction in AF layers. The presence of a kind of appropriate ionic-crystal layers in the structure can support negative refraction for the pumping wave and positive refraction for the SH wave, so the SHG is greatly amplified in the vicinity of each AF resonant frequency. For the composite structure FeF2/TlBr, we found that the SH output is about 8 times higher than that of the FeF2 bulk in the same frequency range. - Highlights: ► Second harmonic generation of an antiferromagnetic/ionic-crystal composite is studied. ► The multilayered composite medium possesses negative refraction for the pumping wave. ► Second harmonic output of the composite is 8 times that of antiferromagnetic bulk.
Primary Subject
Source
S0304-8853(11)00778-5; Available from http://dx.doi.org/10.1016/j.jmmm.2011.11.012; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 324(6); p. 1214-1217

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AbstractAbstract
No abstract available
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Journal Article
Journal
Weld. J. (N. Y.); v. 50(12); p. 833-839
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AbstractAbstract
No abstract available
Original Title
Vliyanie davleniya na ehlektrodvizhushchuyu silu ehlektrokhimicheskikh tsepej Cd/CdI2, Hg2I2/Hg
Primary Subject
Source
Deposited article; for English translation see the journal Russ. J. Phys. Chem.
Record Type
Journal Article
Journal
Zhurnal Fizicheskoj Khimii; v. 46(8); p. 2161-2162
Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
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