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Wexler, Sol; Young, C.E.
Energy Research and Development Administration, Washington, D.C. (USA)
Energy Research and Development Administration, Washington, D.C. (USA)
AbstractAbstract
[en] Description is given of method for separating a specific isotope from a mixture of isotopes of an actinide element present as MF6, wherein M is the actinide element. It comprises: preparing a feed gas mixture of MF6 in a propellant gas; passing the feed gas mixture under pressure through an expansion nozzle while heating the mixture to about 6000C; releasing the heated gas mixture from the nozzle into an exhaust chamber having a reduced pressure, whereby a gas jet of MF6 molecules, MF6 molecular clusters and propellant gas molecules is formed, the MF6 molecules having a translational energy of about 3 eV; converting the MF6 molecules to MF6 ions by passing the jet through a cross jet of electron donor atoms so that an electron transfer takes place between the MF6- molecules and the electron donor atoms whereby the jet is now quasi-neutral, containing negative MF6- ions and positive donor ions; passing the quasi-neutral jet through a radiofrequency mass filter tuned to separate the MF6 ions containing the specific isotope from the MF6- ions of the other isotopes and neutralizing and collecting the MF6 molecules of the specific isotope
[fr]
On decrit un procede pour separer un isotope particulier d'un melange d'isotopes d'un actinide present sous la forme MF6, formule dans laquelle M est l'actinide. Il est caracterise par la preparation d'un melange gazeux d'alimentation de MF6 dans un gaz propulseur; l'envoi du melange gazeux d'alimentation sous pression a travers une tuyere de detente tout en chauffant le melange a environ 6000C; l'envoi du melange gazeux chauffe sortant de la tuyere dans une chambre d'echappement dans laquelle est etablie une pression reduite afin de former un jet de gaz de molecules de MF6, de groupes moleculaires MF6 et de molecules du gaz propulseur, ces molecules de MF6, ayant une energie d'environ 3 eV; la conversion des molecules de MF6 en ions MF6- par passage du jet a travers un jet transversal d'atomes donateurs d'electrons afin qu'un transfert d'electrons ait lieu entre les molecules de MF6 et les atomes donateurs d'electrons de facon que le jet soit alors quasi neutre, contenant des ions MF6- negatifs et des ions donateurs positifs; l'envoi du jet quasi neutre a travers un filtre de masse haute frequence accorde pour separer les ions MF6- contenant l'isotope particulier des ions MF6- des autres isotopes presents dans le melange; et la neutralisation et la captation des molecules de MF6 de l'isotope particulierOriginal Title
Procede pour la separation des isotopes; Pu and U isotopes
Primary Subject
Source
13 May 1976; 14 p; FR PATENT DOCUMENT 2311576/A/; Available from Institut National de la Propriete Industrielle, Paris (France); Priority claim: 23 May 1975, US.
Record Type
Patent
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Nagata, Tetsushi
Proceedings of 12th NIRS seminar on progress of isotope tracer techniques in biology and basic medicine
Proceedings of 12th NIRS seminar on progress of isotope tracer techniques in biology and basic medicine
AbstractAbstract
[en] The techniques of proving soluble labeled compounds by radioautography with an optical or an electron microscope are described, and the various problems in their treatment are discussed: sedimentation fixation, freezing fixation, cryo-sectioning, freeze-substitution embedding, freeze-dry embedding, dry-sectioning, and emulsion dry application. The problem common to all the techniques, to which careful attention must be paid, is to obtain a radioautogram retaining the soluble labeled compound in a localized position as far as possible by preventing its dissolving-out and diffusion. It is extremely difficult to decide which of the techniques should be actually applied. This also differs with the chacteristics of individual labeled compounds. Therefore, the decision must be made by fully considering the chemical and physical characteristics of the compounds. (J.P.N.)
Source
National Inst. of Radiological Sciences, Chiba (Japan); 285 p; 1982; p. 43-57; 12. NIRS seminar on progress of isotope tracer techniques in biology and basic medicine; Anagawa, Chiba (Japan); 4-5 Dec 1980
Record Type
Report
Literature Type
Conference
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AbstractAbstract
[en] The data on techniques for material preparation for isotopic analysis of separate elements and on standards used, are presented. The main processes bring aboUt fractionation of itotopes of each of the elements considered, are discussed. Isotopic properties of hydrogene carbon, oxygen, sulfur, selenium, nitrogen, silicon, boron, alkaline earth and alkali metals, are ionsidesed
Original Title
Izotopnye svojstva otdel'nykh ehlementov
Primary Subject
Source
Goettingen Univ. (Germany, F.R.); p. 30-62; 1983; p. 30-62; Mir; Moscow (USSR); Translation from English.
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Book
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AbstractAbstract
[en] In the present letter we examine an isotope-separation mechanism in the positive column of a dc discharge for the case of a relatively low pressure, at which the ion mean free path is much longer than the radius of the discharge tube and at which the particle collision rate in the volume is low in comparison with the rate at which the particles collide with the wall
Primary Subject
Source
Cover-to-cover translation of Pis'ma v Zhurnal Tekhnicheskoj Fiziki (USSR).
Record Type
Journal Article
Journal
Soviet Technical Physics Letters; ISSN 0360-120X;
; v. 8(11); p. 553

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Mills, T.R.; McInteer, B.B.; Montoya, J.G.
Synthesis and applications of isotopically labelled compounds 1988
Synthesis and applications of isotopically labelled compounds 1988
AbstractAbstract
[en] Sulfur and selenium isotopes are used for labeled compounds and as precursors for radioisotope production; however, both limited availability and high costs are problems. A new method is needed for large-scale separation of theses isotopes. Experimental distillation columns were used to measure isotopic separations for sulfur and selenium compounds. The maximum total isotope separations of 32S vs. 34S were 1.127 for H2S, 1.048 for COS, 0.838 for SF4, and 1.058 for CH3SH. Relative volatilities of 32S and 34S are 1.0006 for COS and 0.9976 for SF4. There is a reverse isotope effect for carbon in COS. No isotopic separation was observed for dimethyl selenide. The lower mass selenium isotopes in H2Se are more volatile. Distillation is a promising method for separating sulfur isotopes on a production scale. Existing distillation technology produces separated isotopes with an effect similar to that found for sulfur in SF4. (author). 8 refs.; 2 tabs
Primary Subject
Source
Baille, T.A. (Washington Univ., Seattle, WA (USA). Dept. of Medicinal Chemistry); Jones, J.R. (Surrey Univ., Guildford (UK). Dept. of Chemistry) (eds.); 860 p; ISBN 0-444-87368-6;
; 1989; p. 773-776; Elsevier; Amsterdam (Netherlands); International symposium on the synthesis and applications of isotopically labelled compounds; Innsbruck (Austria); 17-21 Jul 1988

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Book
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AbstractAbstract
No abstract available
Original Title
Khromatograficheskoe razdelenie smesej R.Z.Eh. s pomoshch'yu fosfororganicheskikh kompleksonov
Primary Subject
Record Type
Journal Article
Literature Type
Progress Report
Journal
Zhurnal Neorganicheskoj Khimii; v. 16(3); p. 651-654
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AbstractAbstract
[en] The textbook is comprised of seven chapters, which give description of computers in a chemical laboratory on introduction, computer and language, interface and network, Mass analysis over structure, using computer and new way for ionization. The method using conversion on theory, convolution, Fourier and Hadamard, Surface analysis on ESCA, UPS, AES, ISS, and SIMS, Analysis by radioactivation with unclear reaction and detection and device, Thermal method of analysis on thermo gravimetric analysis and differential thermal analysis, Experiment technology of gas-chromatography with reference and about gas-chromatography.
Primary Subject
Source
May 1989; 729 p; Donghagisul press; Seoul (Korea, Republic of); 419 refs, 336 figs, 64 tabs
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Book
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AbstractAbstract
[en] The isotherms of systems CdX2-NH4X-H2O (X=Cl, Br, J) at 25 deg C have been obtained. The composition of formed double compounds in systems has been defined. The steam tension over triple saturated solution of studied systems has been defined as well.
Original Title
Izuchenie rastvorimosti v sistemakh CdX2-NH4X-H2O (X=Cl, Br, J) pri 25 deg C
Primary Subject
Source
250 p; 1972; p. 240-248
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Book
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AbstractAbstract
[en] Iodine-Sulfur (IS) cycle is one of the most promising options for the thermo-chemical water splitting technology for the massive production of hydrogen using the high temperature thermal energy from nuclear reactors. This cycle was originally studied in the 1980's by General Atomic Corp. (GA) Neumann's NRTL model has been widely used in the distillation column evaluations and flow sheet developments of the HI section in the thermo-chemical water splitting cycle. CEA had studied the HI section distillation column evaluation with the chemical process simulator PROSIM using Neumann's NRTL model. HI-section of SI cycle with reactive distillation has chosen Neumann's NRTL model with his binary parameters to predict the system pressure in distillation
Primary Subject
Source
Korean Nuclear Society, Daejeon (Korea, Republic of); [1 CD-ROM]; 2007; [2 p.]; 2007 spring meeting of the KNS; Jeju (Korea, Republic of); 10-11 May 2007; Available from KNS, Daejeon (KR); 4 refs, 3 figs, 1 tab
Record Type
Miscellaneous
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AbstractAbstract
[en] A 2-D optimization of quasi-ideal cascade for multi-component isotope separation has been conducted by using the minimum total flow in cascade as an optimization criterion and as optimization parameters the target isotope concentration in a waste flow and the parameter M* determining the flow distribution in cascade were selected. According to the result of optimization it is indicated that there is an optimum combination of the target isotope concentration in a waster flow and the value of M* while the target isotope is enriched to a given concentration and under the optimum combination the total flow in cascade is minimum. (authors)
Primary Subject
Source
3 figs., 3 tabs., 22 refs.
Record Type
Journal Article
Journal
Chinese Journal of Nuclear Science and Engineering; ISSN 0258-0918;
; v. 28(1); p. 86-91

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