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AbstractAbstract
[en] The anomalous reductions in the energy band gap of the chalcopyrite semiconductors as compared to their relative binary analogs are estimated quantitatively by using a simple relation that involves quantum defect electronegativity scale and the average principal quantum number. The chemical and the structural contribution to this anomaly is discussed in details and it is shown that the relation can be easily extended to explain the variation in the band gap of some cross-substitutional alloys
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Journal Article
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Nuovo Cim., D; CODEN NCSDD; v. 9(2); p. 163-173
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No abstract available
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Rio Grande do Sul Univ., Porto Alegre (Brazil); Sociedade Brasileira de Fisica, Rio Grande do Sul; 78 p; 1982; p. 68; 1. National Meeting of Moessbauer Spectroscopy; Porto Alegre, RS (Brazil); 23-24 Sep 1982; Published in summary form only.
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Miscellaneous
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Bendall, Chris; Lahaye, Yann; Fiebig, Jens; Weyer, Stefan; Brey, Gerhard Peter, E-mail: bendall@em.uni-frankfurt.de2006
AbstractAbstract
[en] A new method for in situ S isotopic analysis was tested using a laser ablation system together with a multi-collector (MC)-ICPMS. The method was tested for the analysis of pyrite, pyrrhotite, chalcopyrite and pentlandite using a large pyrite crystal as an in-house standard. Repeated measurements of Py, Pn, Po and Cpy provide an average internal precision of less than 0.1 per mille (2σ). The method was also applied to a pyrite-bearing orogenic Au deposit to display the ability of the method to resolve minor variations in δ 34S across growth zoning in pyrite
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32. International Geological Congress (IGC): Symposium on frontiers in analytical geochemistry; Florence (Italy); 20-28 Aug 2004; S0883-2927(06)00052-7; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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[en] Geological features of antimony ores are summarized based on previous studies. Stibnite ores and pyrites are major minerals of these ores. Although the ore bodies are diverse in shapes, they are mostly strati form-like and their formation is significantly controlled by their structures. (paper)
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5. International Conference on Advanced Composite Materials and Manufacturing Engineering; Xishuangbanna (China); 16-17 Jun 2018; Available from http://dx.doi.org/10.1088/1757-899X/394/5/052076; Country of input: International Atomic Energy Agency (IAEA)
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IOP Conference Series. Materials Science and Engineering (Online); ISSN 1757-899X;
; v. 394(5); [4 p.]

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[en] Different degrees of similarity between inorganic crystal structures are defined concisely and examples are presented that illustrate their practical application. A notation giving the coordination of atoms is presented together with some basic rules for developing crystal-chemical formulae and the Bauverband description of inorganic structure types. Typical examples of the nomenclature are: pyrite Fe[6o]{g}[S2[3;1)t]], F(□2l)+F'FeS2 Paanti 3; spinel Mg[4]Al2[6]O4, ∞3[Mg[4t]Al2[6o]O4[1,3;12co], F'''222+C, T'MgAl2O4 Fdanti 3m. (orig.)
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Journal Article
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Acta Crystallographica, Section A: Foundations of Crystallography; ISSN 0108-7673;
; CODEN ACACE; v. 46(1); p. 1-11

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Wojnarowska, A.; Dziel, T.; Galazka-Friedman, J.; Karwowski, L., E-mail: aga_wojnarowska@interia.pl2008
AbstractAbstract
[en] For Moessbauer studies of the Morasko meteorite three different samples were isolated: troilite, kamacite and taenite. Investigated spectra revealed new mineralogical phases: taenite, tetrataenite and antitaenite. That is first such identification in meteorite found in Poland.
Source
ICAME 2007: 29. international conference on the applications of the Moessbauer effect; Kanpur (India); 14-19 Oct 2007; Copyright (c) 2008 Springer Science+Business Media B.V.; Country of input: International Atomic Energy Agency (IAEA)
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AbstractAbstract
[en] CuInsub(1-x)Fesub(x)Te2 crystal samples with x varying from 0 to 1 have been grown by a programmed-directional-freezing technique. All compounds with x<=0.3 had a single-phase chalcopyrite structure, whereas secondary-phase formation has been observed for x>0.3. Indications of anomalous behaviour in the electrical and magnetic properties at x approx.= 0.1 could be explained due to the delocalization of d electrons originating from the p/d mixing and due to the strong covalence of the chalcopyrite compounds
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5. International Conference on Ternary and Multinary Compounds; Cagliari (Italy); 14-16 Sep 1982
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Journal Article
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Nuovo Cim., D; v. 2(6); p. 1695-1700
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AbstractAbstract
[en] Thirty eight lead isotope analyses made on the Devonian sulphide mineralization of Chessy (Rhone) provide new data on the composition and sources of the hydrothermal fluids that gave rise to the massive sulphide ores of the Brevenne volcanosedimentary district. A partial mantle origin is indicated for the main episode of mineralization, with a remarkable homogeneity in the isotopic signatures of the different ores of the Chessy massive sulphide deposit (galenas with 206Pb/204Pb = 18.163 and 207Pb/204Pb = 15.558). This mantle contribution resulted from leaching, by the mineralizing fluids, of the tholeiitic facies of the underlying volcanic pile. A second episode of mineralization, also associated with submarine silicic volcanic activity, did not give rise to economic concentrations. It is characterised by lead isotope signatures that are more radiogenic (206Pb/204Pb > 18.34 and 207Pb/204Pb > 15.63) without mantle participation
[fr]
Trente-huit analyses isotopiques du plomb, effectuees sur les mineralisations sulfurees devoniennes de Chessy (Rhone), apportent de nouvelles donnees sur les fluides hydrothermaux qui sont a l'origine des amas sulfures du district volcano-sedimentaire de la Brevenne et sur leurs sources. Une origine partiellement mantellique est ainsi mise en evidence pour l'evenement mineralisateur principal, avec une remarquable homogeneite des signatures isotopiques des differents minerais de l'amas de Chessy (galenes a 206Pb/204Pb = 18,163 et 207Pb/204Pb = 15,558). Cette composante mantellique resulte du lessivage par les fluides mineralisateurs des termes tholeiitiques de la pile volcanique sous-jacente. Un second evenement mineralisateur egalement associe a l'activite volcanique acide sous-marine ne donne pas de concentrations economiques. Il est caracterise par des signatures isotopiques du plomb plus radiogeniques, sans participation mantelliqueOriginal Title
Geochimie isotopique du plomb du gisement de Chessy et des mineralisations volcanosedimentaires de la serie de la Brevenne (Massif central). Implications metallogeniques et consequences pour l'exploration
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CONTRACT MA1M-0030F (CD)
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[en] The determination of Moessbauer spectra for two groups of samples are introduced. One group is gold bearing fractural quartzvein type and altered type with different phases of mineralization. In that group, 11 samples are collected in defferent positions in the midpart of No.1 body of Xincheng goldmine and 8 samples are collected in Shangdong Linglong mine and Xincheng mine. The other group consists of 5 samples of intact rocks in the drill holes of ZK 103 and ZK 92 in profile 183. The corresponding variation can be observed in spectral width and the probability of recoilless for pyrite samples with different phases of mineralization. The data are useful for studing mechanism of mineralization of goldmine. This is a priliminary exploration for giving a quantitative indication of mineralization and alteration
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Amari, S.; Méçabih, S.; Abbar, B.; Bouhafs, B., E-mail: siham_amari@yahoo.fr2013
AbstractAbstract
[en] By employing the first-principles method of the full potential linear augmented plane waves plus the local orbitals (FP−L/APW+lo) within the generalized gradient approximation for the exchange and correlation potential, the structural, electronic, and magnetic properties of chalcopyrite compound CdCrO2 are investigated. In order to take into account the strong on-site Coulomb interaction, we also performed the generalized gradient approximation plus the Hubbard correlation terms. We systematically study how the exchange interactions and magnetic moments of CdCrO2 are affected by the different choice of U as well as the exchange correlation potential. We have also carried out the pressure effect on the magnetic properties. - Highlights: ► The calculation of the exchange constants. ► The pressure dependence of the magnetic properties. ► The exchange correlation potential effect on the magnetic properties.
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S0304-8853(12)00768-8; Available from http://dx.doi.org/10.1016/j.jmmm.2012.09.027; Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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