[en] In situobservation of amorphous calcium carbonate (ACC) confined in ~500 pL emulsion droplets allows determination of the timing of individual crystal nucleation events. Statistical analysis of events in hundreds of droplets establishes an upper limit for the steady-state nucleation rate of 1.2 cm^-3s^-1for the crystallization from ACC.

[en] Lactic acid bacteria (LAB) have been used for food fermentation due to its fermentative ability to improve and enhance the quality of the end food products. However, the performance of LAB is affected as fermentation time elapsed because the microbial growth is inhibited by its end product, for example lactic acid. In this study, a new approach was introduced to reduce the product inhibition effect using CaCO_3 which is encapsulated in spherical liquid core capsules of diameter 3.5 mm and 3.6 mm produced through extrusion dripping method. The results showed that the pH and lactic acid concentration of LAB fermentation was well maintained by the capsules. The results of the fermentation conducted to control pH and lactic acid concentration using the capsules were better than those of the control set and comparable with that of the free CaCO_3 set. In addition, the viable cell concentration of L. casei shirota was high at the end of fermentation when the fermentation was conducted using the capsules. The results of this study suggested that the capsules have high potential to be applied for pH and lactic acid level control in LAB fermentation for various productions. (author)

[en] In order to study the composite fouling characteristics of crystallization and particulate, the fouling characteristics of calcium carbonate (CaCO3) and nanometer magnesia in the alternating elliptical axis tube were investigated experimentally. The results show that CaCO3 has obvious effect on the inhibition of the formation of particulate fouling. The asymptotic value of fouling resistance of the nanometer magnesia is the highest and the CaCO3 is the lowest, and the composite fouling is between them. The fouling rate and the asymptotic value of composite fouling resistance decrease with the increase of the CaCO3 concentration. The time reaches to the asymptotic value of the three experiments are similar. The variation of nanometer magnesia concentration has greater influence than the CaCO3 concentration on the asymptotic value of composite fouling. The fouling rate and the asymptotic value of composite fouling resistance increase obviously with the increase of the nanometer magnesia concentration

[en] The isothermal crystallization time of polypropylene/nano calcium (PP/CaCO₃) and polypropylene/attapulgite (PP/ATP) under static and dynamic conditions were investigated by using differential scanning calorimeter and Rheological experiments. Relatively, in static conditions, the calcium carbonate was easier to accelerate the crystallization process due to its shape. In the shear field the attapulgite is more advantageous to shorten crystallization time indicating that the attapulgite dispersed in the PP matrices confined the PP chains and hindered the movement of the PP chains. (paper)

[en] Biominerals, the mineralized tissues of animals, plants, and microorganisms, have inspired humanity with their properties and forms since prehistory. Bones and shells have been used for tools, for currency, for symbolic objects and for art in every culture. Both the fascination and the importance that biominerals present for science are made clear in Darwin's nineteenth-century writings, and in D'Arcy Wentworth Thompson's 1917 On Growth and Form, with its memorable cover illustration of the multi-chambered calcium carbonate nautilus shell. Biomineralization is now a field of study in its own right

[en] The processes based on the separation by membranes seem to become very powerful tools for the purification and the retraining of the fluids. Competed by the inverse osmosis in the domain of the desalination of waters, the electrodialysis (ED) occupies a large place in the agro-alimentary industries to treat the co-products on the one hand and to contribute to the retraining of containing sewages of the heavy metals and toxic, on the other hand. Although it is appreciable for cost and reliability in several domains, the ED suffers to scaling problem caused by the concentration of some ions. Since the technique is used currently for the desalination of water in some industries, we have opted to study mechanisms of membrane scaling by calcium carbonate, one of salts the more frequently met in the stations of desalination in Tunisia. The survey uses a method of accelerated scaling of a pilot unit of electrodialysis. By means of this method, we studied the effect of the initial pH and the composition of water on the kinetics of the scaling formation. The treated waters are synthetic solutions. The results showed that the CO₂ quantity initially dissolved in the solutions is an important factor in the scaling process. According to the composition of water, domains of CO₂ pressure were defined in whom a small variation can generate the rupture of the metastability state in the compartment of concentration and provoke CaCO₃ nucleation in the compartment of concentration and/or on the membranes and conducts. The presence in solution of magnesium in only a Ca/Mg ratio of 0,5 delayed considerably the CaCO₃ nucleation. This ratio is considered like a low bottom limit of magnesium action, ion to natural inhibitory effect present in the natural waters.

[en] The number of factories and home industries, both upper and lower middle class certainly adds waste generated, resulting in environmental pollution. The development of buildings is one of the largest contributors to global warming. For that, it takes technological innovations that lead to the criteria of green building. The application of green material is important aspects of environmentally friendly development, the selection of materials on the green material criteria of both roles should be applied continuously in order to realize the environmental sustainability of the material. Utilization Waste eggshell and bagasse which is a community waste, has the potential to become innovative environmentally friendly building materials. The eggshell is composed of 94% calcium carbonate, 1% magnesium carbonate, 1% calcium phosphate, and 4% organic material, especially protein, while the bagasse has a high content of silica (SiO2). In this study, the compounds are used as raw material for making alternative drywall in the form of DECO FRECASE. DECO FRECASE is an innovation of environmentally friendly building materials as an interior wall construction. Through DECO FRECASE, it is expected that building material innovation in Indonesia can be improved and of course environmental problems can be minimized by utilizing it as raw material for building construction. (paper)

[en] Scale formation is a serious problem encountered in many industrial plants including natural water desalination units. Scales are mainly formed by calcium carbonate [1]. In some ground waters, the presence of some species such as Mg²⁺, SO₄^2- and Fe²⁺ influence significantly the CaCO₃ precipitation. In the present work, the effects of Fe²⁺ and Fe³⁺ on the kinetic precipitation and the microstructure of CaCO₃ were investigated. The calcium carbonate was precipitated by using the degassing CO₂ method. This technique is based on the elimination of the dissolved carbonic gas CO₂ in solution by air or N₂ bubbling according to the following precipitation reaction of calcium carbonate: Ca²⁺2HCO₃^-→CaCO₃+(s)+CO₂↑+H₂O. In ground Water, iron usually occurs in its ferrous state (Fe²⁺), but once exposed to air, it will be oxidized to Fe³⁺. The effect of iron (II) on the carbonate calcium precipitation was been reported under an azote bubbling condition. The experimental procedure used in this work allowed us to study the effect of Fe(II) and Fe(III) on the CaCO₃ precipitation. It was shown that the iron ions with these different degrees of oxidation (II or III) improved the kinetic precipitation of calcium carbonate. XRD analysis shows that the presence of iron (II) favoured the formation of aragonite instead of vaterite phase. The microscopic observation by SEM showed that the presence of the iron (II) in the solution affects the morphology and the size of the carbonate calcium precipitate.

[en] Gallstones of seven patients were collected from different parts of North West Frontier and Punjab provinces. These stones were analyzed using Liebermann-Burchard method, estimation technique and Microlab-200 for cholesterol, calcium carbonate (CaCO/sub 3/) and bilirubinate respectively. The levels of cholesterol bilirubinate and CaCO/sub 3/ were found in the ranges of 50-81, 12-40 and 7-19% respectively. All of the stones were found to be mixed type stones that contain cholesterol, bilirubinate and calcium carbonate. The structures of the stones are also shown in the picture, which confirm our analysis data. Possible reasons, which cause formation of gallstones, are discussed in this paper. (author)

[en] Understanding of soil phosphorus (P) adsorption chemistry is essential for evolving best fertilizer management practices aimed at enhancing fertilizer P use efficiency and environment quality. Soil chemical parameters which govern P adsorption maxima and binding strength in calcareous and non-calcareous soils were determined. Five soils representing three different parent materials i.e. mixed mineralogy alluvium, loess and non calcareous sandstone were sampled at genetic horizons in each profile. Phosphorus adsorption isotherm was developed for each of the 32 soil samples by equilibration of two g air dry soil with 0 to 4000 mgl/sup -1/ (0 to 125 mM) P in 20 ml of 10 mM KCI; and fitted to Langmuir and Freundlich equations. The chemical parameters i.e. pH, CaCO/sub 3/, total and dissolved organic carbon, exchangeable calcium, dithionite extractable iron (Fe/sub d/) and aluminum (AI/sub d/), oxalate extractable iron (Fe/sub o/) and aluminum (Al/sub o/) and as a test for plant available P extractable with NaHCO/sub 3/ were determined. The Fruendlich equation, an empirical relation between adsorbed and solution P, fitted the adsorption isotherms better than the Langmuir equation which relates adsorption to solid surface coverage by adsorbate. Adsorption maxima at low affinity sites positively correlated with soil CaCO/sub 3/ due to precipitation as Ca-P and to extractable iron oxide; and the binding strength of high affinity (kJ sites correlated positively with soil Fe/sub d/, Al/sub o/, AI/sub d/, and crystalline iron oxide (Fe/sub d/-Fe/sub o/) contents. The Freundlich parameter b/sub r/, adsorption exponent which signifies sorption intensity also positively correlated with soil Fe/sub d/, Fe/sub cr/ and Aid contents. Phosphorus adsorption at its low concentration in equilibrium solution seems to be governed by soil iron oxides and precipitation as Ca-P is important only at high P concentration, less frequently achieved in farm fields. (author)