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Chanbi, Z.; Paynter, R.W., E-mail: Royston_Paynter@emt.inrs.ca
AbstractAbstract
[en] We report our investigation of the dependence of the profile extracted from ARXPS data on the value of the regularization parameter α. We argue that a choice based upon the L-curve criterion, which does not require knowledge of the variances in the data, is less satisfactory than an approach based on choosing α such that χ2/N = 1
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S0368-2048(08)00029-7; Available from http://dx.doi.org/10.1016/j.elspec.2008.04.005; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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Journal of Electron Spectroscopy and Related Phenomena; ISSN 0368-2048;
; CODEN JESRAW; v. 164(1-3); p. 28-33

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Lubenchenko, A. V.; Batrakov, A. A.; Ivanov, D. A.; Lubenchenko, O. I.; Lashkov, I. A.; Pavolotsky, A. B.; Schleicher, B.; Albert, N.; Nielsch, K., E-mail: LubenchenkoAV@mpei.ru
AbstractAbstract
[en] X-ray photoelectron spectroscopy (XPS) depth chemical and phase profiling of air-oxidized niobium nanofilms has been performed. It is found that oxide layer thicknesses depend on the initial thickness of the niobium nanofilm. The increase in thickness of the initial Nb nano-layer is due to increase in thickness of an oxidized layer.
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Copyright (c) 2018 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA)
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AbstractAbstract
[en] Competitive adsorption of As(V) and Sb(V) at environmentally relevant concentrations onto ferrihydrite was investigated. Batch experiments and XPS analyses confirmed that in a binary system, the presence of Sb(V) exhibited a slight synergistic effect on As(V) adsorption. XPS analyses showed that As(V) and Sb(V) adsorption led to obvious diminishment of Fe–O–Fe and Fe–O–H bonds respectively. At pH of 9, a more significant decrease of Fe–O–Fe was observed in the binary system than that in a single system, indicating that As(V) displayed an even stronger interaction with lattice oxygen atoms under competitive conditions. Basically, ionic strength demonstrated a negligible or positive influence on As(V) and Sb(V) adsorption in binary system. Study of adsorption sequence also indicated that the presence of Sb(V) showed a promotion effect on As(V) adsorption at neutral pHs. Considering that co-contamination of As and Sb in waters has been of great concern throughout the world, our findings contributed to a better understanding of their distribution, mobility, and fate in environment.
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46. congress of the French Group of Pesticide Research (Groupe Francais des Pesticides, GFP); Bordeaux (France); 15-17 May 2016; Copyright (c) 2018 Springer-Verlag GmbH Germany, part of Springer Nature; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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Conference
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Environmental Science and Pollution Research International; ISSN 0944-1344;
; CODEN ESPLEC; v. 25(15); p. 14585-14594

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AbstractAbstract
[en] Highlights: • Method to obtain wide ranges of water contact angles (CA) ∼5° to ∼149° proposed. • Reported effect of length of silicon nanowires and/roughness on final water CA. • Reported how nanoscale variation in PDMS thickness effects hydrophobic recovery. • Studied evolution of water CA vs. time for PDMS coated Si/Si nanowire samples. The ability to modify the contact angle (CA) of water on silicon has applications ranging from thermal management of electronics to miniaturized biomedical devices. Here, we report ∼30 ± 1° variation in superhydrophobic CA on silicon nanowires (NWs) coated with few nm of polydimethylsiloxane (PDMS), using a simple and stable plasma treatment. The variation in CA arises from choosing NWs of different lengths. We characterize the surfaces using a combination of X-ray photoelectron spectroscopy and other techniques. Together with CA available from similar treatment on bulk silicon, it is possible to non-lithographically create regions of diverse CA, from ∼5 to 149 ± 1°.
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S0009261416000804; Available from http://dx.doi.org/10.1016/j.cplett.2016.01.058; Copyright Copyright (c) 2016 Elsevier B.V. All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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AbstractAbstract
[en] It is shown that both sp2 and sp3 hybridized structures form in samples modified with fullerene and prepared by fusion, which is indicative of the carbon nanostructure formation. In the samples modified with graphite and prepared by fusion, only graphite-like structures form
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ICESS-10: International conference on electronic spectroscopy and structure; Foz do Iguacu, PR (Brazil); 28 Aug - 1 Sep 2006; S0368-2048(06)00209-X; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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Conference
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Journal of Electron Spectroscopy and Related Phenomena; ISSN 0368-2048;
; CODEN JESRAW; v. 156-158; p. 191-194

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Woicik, J.; Fischer, D.; Vescovo, E.; Arena, D.; Starr, D.; Wells, B.; Fadley, C.
Brookhaven National Laboratory National Synchrotron Light Source (United States). Funding organisation: DOE - Office Of Science (United States)
Brookhaven National Laboratory National Synchrotron Light Source (United States). Funding organisation: DOE - Office Of Science (United States)
AbstractAbstract
[en] The third international workshop on hard X-ray photoelectron spectroscopy (HAXPES 2009) was held at Brookhaven National Laboratory, Upton, New York, from May 20-22, 2009. This three-day workshop brought together approximately 100 scientists from 14 countries to discuss progress and future prospects for this rapidly developing field of research. The conference was sponsored by the National Synchrotron Light Source, the National Synchrotron Light Source-II Project, Brookhaven National Laboratory Condensed Matter Physics and Materials Science Department, and the National Institute of Standards and Technology.
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BNL--95843-2011-JA; AC02-98CH10886
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Journal Article
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Synchrotron Radiation News; ISSN 0894-0886;
; v. 23(1); p. 19-21

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Ilton, Eugene S.; Boily, Jean F.; Buck, Edgar C.; Skomurski, Frances N.; Rosso, Kevin M.; Cahill, Christopher L.; Bargar, John R.; Felmy, Andrew R.
Pacific Northwest National Lab., Richland, WA (United States), Environmental Molecular Sciences Laboratory (US). Funding organisation: US Department of Energy (United States)
Pacific Northwest National Lab., Richland, WA (United States), Environmental Molecular Sciences Laboratory (US). Funding organisation: US Department of Energy (United States)
AbstractAbstract
[en] The heterogeneous reduction of UVI to UIV by ferrous iron is a potentially key process influencing the fate and transport of U in the environment. The reactivity of both sorbed and structural FeII has been studied for numerous substrates, including magnetite. The results from UVI-magnetite experiments have been variable, ranging from no reduction to clear evidence for the formation of UIV. In this contribution, we used XAS and high resolution (+cryogenic) XPS to study the interaction of UVI with nano-particulate magnetite. The results indicated that UVI was partially reduced to UV with no evidence of UIV. However, thermodynamic calculations indicated that mixed-valence U phases with average oxidation states below (V) should have been stable, indicating that the system was not in redox equilibrium. A reaction pathway that involves incorporation of U and stabilization of UV and UVI in secondary phases is invoked to explain the observations.
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PNNL-SA--66737; 19823; KC0303020; AC05-76RL01830
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Journal Article
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Environmental Science and Technology; ISSN 0013-936X;
; v. 44(1); p. 170-176

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AbstractAbstract
[en] We report in this paper an original way to covalently bind the macrocyclic ligand, 1,4,8,11-tetraazacyclotetradecane (cyclam), through diazonium salt chemistry, on the surface of carbon screen-printed electrodes (SPEs). The in situ synthesis of the diazonium salt obtained from the amine precursor derived from the cyclam and its electrografting are described. X-ray Photoelectron Spectroscopy was used to characterize this functionalized surface. Owing to the strong cyclam–Cu(II) affinity, the so called SPE-cyclam can be used as electrochemical sensors for Cu(II) determination at trace levels. The influence of electroanalysis parameters such as the accumulation time and the pH of the medium were investigated. An interference study was carried out with numerous metallic cations and few interference was found for Cu(II) quantification. The described method provided a limit of detection and a limit of quantification of 1.3 × 10"−"8 M and 4.0 × 10"−"8 M, respectively. Interference study and performances show that SPE-cyclam could be considered as efficient sensors for environmental analysis.
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S0013-4686(16)30712-5; Available from http://dx.doi.org/10.1016/j.electacta.2016.03.141; Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Dalai, M.K.; Kundu, R.; Pal, P.; Bhanja, M.; Sekhar, B.R.; Martin, C., E-mail: dalaimk@nplindia.org
AbstractAbstract
[en] Highlights: → Using X-ray photoelectron spectroscopy, we have studied the Mn 2p, Ca 2p, and Pr 4d core levels of Pr1-xCaxMnO3 (x = 0.2, 0.33, 0.4 and 0.84) as a function of x at room temperature as well as 77 K. → Suppression of chemical potential shifts have been observed at 77 K compared to that of room temperature spectra. → We have discussed this result by considering the concept of phase separation. - Abstract: We have studied the Mn 2p, Ca 2p, and Pr 4d core levels of Pr1-xCaxMnO3 (x = 0.2, 0.33, 0.4 and 0.84) as a function of x using X-ray photoelectron spectroscopy both at room temperature as well as 77 K. Suppression of chemical potential shifts have been observed at 77 K compared to that of room temperature spectra. We have discussed this result by considering the concept of phase separation.
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S0925-8388(11)01026-7; Available from http://dx.doi.org/10.1016/j.jallcom.2011.05.003; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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AbstractAbstract
[en] Contact resistance (R C) is a major limiting factor in the performance of graphene devices. R C is sensitive to the quality of the interface and the composition of the contact, which are affected by the graphene transfer process and contact deposition conditions. In this work, a linear correlation is observed between the composition of Ti contacts, characterized by x-ray photoelectron spectroscopy, and the Ti/graphene contact resistance measured by the transfer length method. We find that contact composition is tunable via deposition rate and base pressure. Reactor base pressure is found to effect the resultant contact resistance. The effect of contact deposition conditions on thermal transport measured by time-domain thermoreflectance is also reported. Interfaces with higher oxide composition appear to result in a lower thermal boundary conductance. Possible origins of this thermal boundary conductance change with oxide composition are discussed. (paper)
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Available from http://dx.doi.org/10.1088/1361-6528/aaaacd; Country of input: International Atomic Energy Agency (IAEA)
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Nanotechnology (Print); ISSN 0957-4484;
; v. 29(14); [7 p.]

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