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AbstractAbstract
[en] The separation of cadmium from indium, zinc and many other elements is considerably improved by eluting these elements with 0.1 M hydrobromic-0.5 M nitric acid solution from a column of AG1-X8 resin. Cadmium is retained very strongly and can be eluted with 2 M nitric acid or 1 M ammonia-0.2 M ammonia nitrate solution. Separations are sharp and quantitative and from microgram amounts up to 2 g of indium and zinc are separated from amounts of cadmium ranging from micrograms up to 100 mg on a 2-g (4.6 ml) resin column. Ga(II), Fe(III), Mn(II), Co(II), U(VI) and Ni(II) can be separated quantitatively from cadmium in the same way. The behaviour of numerous elements is discussed, with special attention to load, and relevant elution curves and results from the analysis of synthetic mixtures are presented. (Auth.)
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Record Type
Journal Article
Journal
Analytica Chimica Acta; ISSN 0003-2670;
; v. 100 p. 577-588

Country of publication
ACTINIDES, AMMONIUM COMPOUNDS, BROMINE COMPOUNDS, CHARGED PARTICLES, CHROMATOGRAPHY, ELEMENTS, HALOGEN COMPOUNDS, HYDROGEN COMPOUNDS, INORGANIC ACIDS, IONS, METALS, NITRATES, NITROGEN COMPOUNDS, ORGANIC COMPOUNDS, ORGANIC POLYMERS, OXYGEN COMPOUNDS, POLYMERS, SEPARATION PROCESSES, TRANSITION ELEMENTS
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