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AbstractAbstract
[en] Compounds of type A2sup(II)Bsub(0.5)sup(I)Bsub(0.5)sup(III)Wsup(VI)O6 can be obtained with Asup(II) = Ba; Bsup(I) = Li, Na and Bsup(III) = La, Nd, Sm, Gd, Y, In, Sc just as with Asup(II) = Sr; Bsup(I) = Li and Bsup(III) = La, Nd, Sm, Gd, Y, In (all cubic ordered perovskites). For the cubic perovskites Sr2Nasub(0.5)Lasub(0.5)WO6 and Sr2Nasub(0.5)Ndsub(0.5)WO6 additional superlattice reflections are observed (a approximately equal to 16.4 A). The compounds Sr2Nasub(0.5)Bsub(0.5)sup(III)WO6 crystallize with Bsup(III) = Sm, Gd in a monoclinic and with Bsup(III) = Y, In in a rhombic distorted perovskite lattice. For the perovskites with A = Sr - dependent on ionic radii of the B ions - two different lattice types are present. (author)
Original Title
Ueber Perowskite A2sup(II)Bsub(0.5)sup(I)Bsub(0.5)sup(III)Wsup(VI)O6
Primary Subject
Record Type
Journal Article
Journal
Zeitschrift fuer Anorganische und Allgemeine Chemie (1950); ISSN 0044-2313;
; v. 440 p. 197-202

Country of publication
ATOMIC RADII, BARIUM COMPOUNDS, CALCIUM COMPOUNDS, CUBIC LATTICES, GADOLINIUM COMPOUNDS, INDIUM COMPOUNDS, INFRARED SPECTRA, LANTHANUM COMPOUNDS, LATTICE PARAMETERS, LITHIUM COMPOUNDS, MONOCLINIC LATTICES, NEODYMIUM COMPOUNDS, ORTHORHOMBIC LATTICES, SAMARIUM COMPOUNDS, SCANDIUM COMPOUNDS, SODIUM COMPOUNDS, STRONTIUM COMPOUNDS, TUNGSTATES, X-RAY DIFFRACTION, YTTRIUM COMPOUNDS
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