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Bergeonneau, P.; Jaouen, C.; Germain, M.; Bathellier, A.
CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92 (France). Dept. de Genie Radioactif1977
CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92 (France). Dept. de Genie Radioactif1977
AbstractAbstract
[en] Uranium, plutonium and neptunium kinetics of transfer between various aqueous nitric solutions and solvents have been measured at the laboratory scale, using a centrifugal contactor especially developed in the laboratory. The transfer kinetics of nitric acid, hexavalent U, tetravalent U, Np and Pu from nitric acid solutions into 30% TBP in r-dodecane and 10% trilaurylamine in r-dodecane have been studied. The effects of rotation speed, temperature, initial nitric acid concentration, metal concentration on extraction and stripping kinetics have been investigated. The results obtained show that TBP extraction and stripping are more rapid than trilaurylamine ones. The low activation energies of transfer reactions with TBP suggest that both in extraction and stripping, the transfer rate is limited by the diffusion of the species in the aqueous and organic phases. For trilaurylamine, the transfer mechanism appears more complex
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1977; 33 p; International solvent extraction conference; Toronto, Ontario, Canada; 9 - 16 Sep 1977
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Report
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Conference
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ACTINIDE COMPOUNDS, AMINES, BUTYL PHOSPHATES, CHARGED PARTICLES, CHELATING AGENTS, ESTERS, HYDROGEN COMPOUNDS, INORGANIC ACIDS, IONS, KINETICS, NITROGEN COMPOUNDS, ORGANIC COMPOUNDS, ORGANIC PHOSPHORUS COMPOUNDS, OXYGEN COMPOUNDS, PHOSPHORIC ACID ESTERS, REACTION KINETICS, SEPARATION PROCESSES, TRANSURANIUM COMPOUNDS
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