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[en] Asymptotic forms for the one-electron two-centre Coulomb problem are used to discuss the properties of pseudocrossings in the correlation diagram for the (Zsub(a)Zsub(b)) sup((Zsub(a) + Zsub(b) - 1)+) system. It is shown that discrepancies in different expressions for the energy gap at a pseudocrossing may be resolved by a proper consideration of the electron wavefunction normalisation. (author)
Journal
Journal of Physics. B, Atomic and Molecular Physics; ISSN 0022-3700; 
; v. 11(20); p. 3563-3571
; v. 11(20); p. 3563-3571