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AbstractAbstract
[en] The possibility of improving the positive electrode characteristics of medium temperature lithium-nitrate element by means of adding alkali metal halogenides into nitrate melt is considered. The experiments have been made at the temperature of 150 deg C in (K, Na, Li) NO3 melts of eutectic composition. It has been found that only at temperatures higher than 250 deg C in nitrate melts containing Li+ and Na+ cations, an interaction of nitrate ions with the added iodides is possible. The interaction does not take place in case of chloride, bromide, and fluoride additions. The waves of halogenide oxidation and reduction of the corresponding halogens have been identified. The analysis of the obtained experimental data shows that halogenide addition into nitrate melt does not result in speed increase of cathodic reduction of nitrate ions or in formation of a new cathode process at more positive potentials. A conclusion is made that halogenide addition into electrolyte of lithium-nitrate current source is inexpedient
Original Title
Khimicheskoe i ehlektrokhimicheskoe povedenie galogenidov v nitratnykh rasplavakh
Primary Subject
Source
For English translation see the journal Sov. Electrochem.
Record Type
Journal Article
Journal
Ehlektrokhimiya; v. 14(6); p. 844-850
Country of publication
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