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AbstractAbstract
[en] The Raman and infrared absorption spectra (up to 30 cm-1) of β-Li Yb(WO4)29 and a spectrum of an isotope-substituted, with respect to lithium, sample have been measured. Frequencies and shapes of normal vibration of two non-equivalent crystal directions have been calculated in a polymer approximation. The system of force constants has been determined. The frequency branches of the vibrations have been calculated when a phase vector changes from S=1 to 100 and atoms displacements. The calculation results have shown that a considerable contribution to the vibrations of end W-O bonds (the region of 900-930 cm-1) is made by the coordinates of the n-O bonds (where M is Li or Yb) elongation and by deformation of the WOM and OMO angles
Original Title
Issledovanie kolebatel'nogo spectra β-LiYb(WO4)2
Primary Subject
Source
For English translation see the journal Russ. J. Inorg. Chem.
Record Type
Journal Article
Journal
Zhurnal Neorganicheskoj Khimii; v. 23(2); p. 369-375
Country of publication
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