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AbstractAbstract
[en] In this thesis, the results of far infrared absorption experiments on solid molecular hydrogen and deuterium are presented. In Chapter I an introduction to the properties of solid molecular hydrogens in given. The experimental system used for the high pressure infrared measurements and the data handling procedures are discussed in Chapter II. The theory of infrared absorption and the averaging of the dipole moment over the motion of the molecules is contained in Chapter III. In this chapter a general sum rule for the integrated absorption is derived. The remaining chapters present the results of the measurements and the discussion. In Chapter IV the author concentrates on the phonon frequencies as a function of ortho-para concentration and density, while in Chapter V measuremtns of phonon lineshape and integrated absorption intensities are presented. Finally, in Chapter VI, a study is given of the phase transition in solid hydrogen and deuterium. This study provides accurate values for the transition temperature as a function of density (in deuterium) and as a function of ortho-para concentration (in hydrogen) as well as the dependence of the order parameter on the temperature and the ortho-para concentration. (Auth.)
Primary Subject
Source
6 Dec 1978; 159 p; Proefschrift (Dr.).
Record Type
Miscellaneous
Literature Type
Thesis/Dissertation
Report Number
Country of publication
ABSORPTION SPECTROSCOPY, CRYSTALS, DENSITY, DEUTERIUM, ELECTRIC DIPOLE MOMENTS, FAR INFRARED RADIATION, FOURIER ANALYSIS, GROUND STATES, HYDROGEN, INFRARED SPECTRA, INTERMOLECULAR FORCES, MICHELSON INTERFEROMETER, MOLECULES, ORDER PARAMETERS, PHASE STUDIES, PHASE TRANSFORMATIONS, PHONONS, POLARIZATION, QUANTUM MECHANICS, SOLIDS, SUM RULES, ULTRALOW TEMPERATURE
DIPOLE MOMENTS, ELECTRIC MOMENTS, ELECTROMAGNETIC RADIATION, ELEMENTS, ENERGY LEVELS, EQUATIONS, HYDROGEN ISOTOPES, INFRARED RADIATION, INTERFEROMETERS, ISOTOPES, LIGHT NUCLEI, MEASURING INSTRUMENTS, MECHANICS, NONMETALS, NUCLEI, ODD-ODD NUCLEI, PHYSICAL PROPERTIES, QUASI PARTICLES, RADIATIONS, SPECTRA, SPECTROSCOPY, STABLE ISOTOPES
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