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AbstractAbstract
[en] The principal immediate objective is the conversion of minor actinides (Pa, Np, Am, Cm and transcurium elements) either to fission products or to major actinides (Th, U and Pu) in a reactor. Various extractants have been suggested for recovery of an Am/Cm/rare earth fraction from the HLW. The most promising seem to be a neutral, bi-functional organophosphorus extractant capable of operating directly on the HLW, and dibutyl butylphosphonate acting on the HLW after acidity reduction and addition of a salting agent (probably aluminium nitrate). For the subsequent separation of Am/Cm from the rare earths there is at present virtually only one possibility, viz. the use of diethylenetriamine-penta-acetate (DTPA) or a related compound, despite certain draw-backs. A preliminary 'exhaustive extraction' for residual U, Np and Pu may precede Am/Cm recovery. Another possible preliminary step is an oxalate precipitation and dissolution cycle. Much development is required before a complete separation flowsheet can be written, and the feasibility (or otherwise) of the separations can be established
Primary Subject
Source
Commission of the European Communities, Ispra (Italy). Joint Research Centre; p. 3-11; 1978; p. 3-11; 1. Technical meeting on the nuclear transmutation of actinides; Ispra, Italy; 16 - 18 Apr 1977
Record Type
Report
Literature Type
Conference
Report Number
Country of publication
ACTINIDES, AMINO ACIDS, BUTYL PHOSPHATES, CARBOXYLIC ACIDS, CHELATING AGENTS, CLEANING, ELEMENTS, ESTERS, METALS, ORGANIC ACIDS, ORGANIC COMPOUNDS, ORGANIC PHOSPHORUS COMPOUNDS, PHOSPHORIC ACID ESTERS, RADIOACTIVE MATERIALS, RADIOACTIVE WASTES, SEPARATION PROCESSES, TRANSPLUTONIUM ELEMENTS, TRANSURANIUM ELEMENTS, WASTES
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