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Hornung, P.A.; Khan, A.D.; Torgeson, D.R.; Barnes, R.G.
Iowa State Univ. of Science and Technology, Ames (USA)1979
Iowa State Univ. of Science and Technology, Ames (USA)1979
AbstractAbstract
[en] Measurements are reported of the proton spin-lattice relaxation time T1 in the tantalun--hydrogen system over the temperature and composition ranges, 770K less than or equal to T less than or equal to 4700K and 0.155 less than or equal to H/Ta less than or equal to 0.677, respectively. In the high temperature, solid-solution (α) phase, the activation energy for hydrogen diffusion determined from the dipolar contribution to T1, shows a weakly increasing trend from 0.134 eV/atom at H/Ta = 0.155 to 0.140 eV/atom at H/Ta = 0.677. Boundaries between ordered hydride phases and the α phase, located by the occurrence of abrupt changes in T1, agree very well with other recent determinations. The quantity (T/sub 1e/T)/sup -1/2/, based on the conduction electron contribution, (T/sub le/)-1, to the relaxation rate (T1)-1, is proportional to the density of states at the Fermi level N(E/sub F/). (T/sub 1e/T)/sup -1/2/ decreases linearly with increasing hydrogen concentration, similarly to its behavior in the V--H and Nb--H systems
Original Title
770K-4700K
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Source
1979; 11 p; Hydrogen in metals international meeting; Muenster, Germany, F.R; 6 - 9 Mar 1979; CONF-790301--2; Available from NTIS., PC A02/MF A01
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Conference
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