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[en] Equilibrium gases, emerging from Knudsen cells, which contained LiCl, ScCl3 or LiCl + ScCl3 respectively, have been analysed by means of a mass spectrometer. The T-dependence leads to the ΔH0-data. The relation of the fragments to the parent molecules LiCl, Li2Cl2, Li3Cl3, ScCl3, Sc2Cl6, Sc3Cl9, LiScCl4, Li2Sc2Cl8 (and LiSc2Cl7) leads to fragmentation factors. By means of these factors the ΔS0-data for gaseous homogeneous reactions could be calculated. (author)
Journal
Zeitschrift fuer Anorganische und Allgemeine Chemie (1950); ISSN 0044-2313; 
; v. 450 p. 88-102
; v. 450 p. 88-102