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AbstractAbstract
[en] The kinetics of the dissolution of plutonium metal in sulfamic acid at varying temperatures was determined. Hydrogen off-gas rates and plutonium concentrations were determined as functions of time for different dissolving conditions. Nominal 2.2 kg Pu buttons (surface area, 171 cm2) should yield solutions containing 190 to 260 g Pu/L and 3.3M sulfamate ion after a one-hour dissolving time at 700C. Hydrogen off-gas rates were calculated to vary from a high of 2.7L of gaseous hydrogen per minute (STP) at the beginning of a dissolving cycle to 50 mL of hydrogen gas per minute at the end of a one-hour dissolving time. Sludge formation, which is a problem at ambient temperatures, does not occur at dissolving temperatures of 60 to 800C. Dissolution curves suggest that the mechanism of dissolution changes at about 50 to 550C. Below this temperature, a surface coating of plutonium hydride may form; above this temperature, plutonium metal appears to be converted directly to Pu3+. 13 figures, 1 table
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Feb 1979; 28 p; Available from NTIS., PC A03/MF A01
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