[en] A new method for the determination of cross sections for K-shell ionization of heavy atoms by charged particles is proposed. The method is based on a comparison of photon lines due to K x-rays and low-energy γ-rays, the latter ones being produced in nuclear Coulomb excitation with accurately known cross sections. This procedure applies within a limited energy range to the study of targets comprising deformed even nuclei, but can also be extended to other targets having Z > or approximately 30. A test of the new technique has been carried out for Gd, W, Th and U natural targets irradiated by 4.75 MeV protons. For Th, also energies of 6.80 to 10.10 MeV were used. The results are briefly discussed with reference to those from other experiments and from various theoretical predictions. (author)